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  • 1985-1989  (2)
  • 1980-1984  (3)
  • 1975-1979  (8)
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Years
Year
  • 1
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Inorganic chemistry 19 (1980), S. 1089-1090 
    ISSN: 1520-510X
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Journal of the American Chemical Society 97 (1975), S. 1754-1760 
    ISSN: 1520-5126
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    European biophysics journal 7 (1981), S. 317-317 
    ISSN: 1432-1017
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Physics
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Springer
    Pflügers Archiv 390 (1981), S. 288-289 
    ISSN: 1432-2013
    Keywords: Voltage clamp ; Myelinated nerve
    Source: Springer Online Journal Archives 1860-2000
    Topics: Medicine
    Notes: Abstract In voltage clamp experiments on myelinated nerve fibres the time resolution of the current measurement is limited by the low-pass characteristics of the internodes. We increased the corner frequency of the current passing internode by grounding one half of this internode externally. Using a simplified equivalent circuit we calculated an increase in the bandwidth of the internode by a factor of about 6. Consequently, the peak value of the recorded capacity current increased while its duration was considerably shortened.
    Type of Medium: Electronic Resource
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  • 5
    ISSN: 1572-8854
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences , Physics
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Springer
    Journal of cancer research and clinical oncology 114 (1988), S. 502-506 
    ISSN: 1432-1335
    Source: Springer Online Journal Archives 1860-2000
    Topics: Medicine
    Notes: Summary The antitumor activity of the four metallocene compounds decaphenylstannocene [η5-(C6H5)5C5]2Sn(II), decabenzylstannocene [η5-(C6H5CH2)5C5]2Sn(II), decaphenylgermanocene [η5-(C6H5)5C5]2Ge(II), and decabenzylgermanocene [η5-(C6H5CH2)5C5]2Ge(II), containing the main group IV elements tin or germanium as the central metal atom and two pentasubstituted cyclopentadienyl ring ligands in sandwich arrangement, were tested against Ehrlich ascites tumor in female CF1 mice. The complexes caused cure rates of 40% to 90% of the animals treated over rather broad dose ranges. With both germanocene complexes, no strong dose-activity relationship was manifest. The toxicity of all four metallocenes was low, the LD10 values of both stannocenes being 460 and 500 mg/kg, and those of both germanocenes higher than 700 mg/kg. Regarding the isolated pentasubstituted cyclopentadiene ligands (C6H5)5C5H and (C6H5CH2)5C5H, these also exhibited antitumor activity which was less pronounced than that of the metal-containing sandwich complexes. Decasubstituted stannocene and germanocene compounds represent a new type of non-platinum group metal antitumor agents structurally differing from known inorganic and organometallic cytostatics.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Springer
    Mineralogy and petrology 23 (1976), S. 137-150 
    ISSN: 1438-1168
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Description / Table of Contents: Summary The orientations of the crystallites in a fibrous halite were determined using an X-ray universal stage method in which for each individual grain the Laue-diagrams of the three symmetry axes, made visible by an image intensifier, were set at the center. The results are presented in an equal-area net using the poles of the corresponding grain's sections in a spherical triangle with the normals to (001), (011) and (111) as corner points. Studies on a thin section perpendicular to the fiber direction revealed a two-fold axis approximately along the fiber direction for about a third of the crystallites. This is qualitatively what is expected from halite vectorial growth rates. The results of sections parallel to the fiber axis are not so clear but do show orientation effects.
    Notes: Zusammenfassung Die Orientierung der Kristallite eines Faserhalites wurde mit einer Röntgen-U-Tisch-Methode bestimmt, indem für jedes Korn die drei Symmetrieachsen des durch einen Bildverstärker sichtbar gemachten Laue-Bildes zentral gestellt wurden. Die Darstellung der Ergebnisse erfolgte in einer flächentreuen Projektion durch Eintragung der Pole der Kornschnittflächen im entsprechenden Präparat in einem sphärischen Dreieck mit den Durchstoßpunkten der Senkrechten auf (001), (011) und (111) als Eckpunkten. Aus der Bearbeitung eines Schnittes senkrecht zur Faserrichtung ergibt sich, daß etwa ein Drittel der Kristallite eine zweizählige Achse nahe zur Faserrichtung hat; das entspricht qualitativ den Erwartungen aus den vektoriellen Wachstumsgeschwindigkeiten beim Halit. Die Ergebnisse aus Schnitten parallel zur Faserachse sind nicht so klar zu interpretieren, jedoch zeigen sich auch hier Orientierungseffekte.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Springer
    Mineralogy and petrology 24 (1977), S. 179-190 
    ISSN: 1438-1168
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Description / Table of Contents: Summary The fabric of an oriented halite rock sample from Niedersachsen-Riedel pit near Wathlingen (Niedersachsen, BRD) was determined by fixing the orientation of 540 grains using a four circle X-ray universal stage. The statistical evaluation leads to weak maxima of the poles of the fourfold axis and shows that the {100} faces lie — more often than purely statistically — parallel to the three macroscopic partition planesL, S andQ which are oriented approximately perpendicular to each other. — Further investigations would be necessary for a genetic interpretation of natural halite fabrics.
    Notes: Zusammenfassung Das Korngefüge einer orientiert entnommenen Halit-Gesteinsprobe aus der Grube Niedersachsen-Riedel bei Wathlingen (Niedersachsen, BRD) wurde durch Festlegung der räumlichen Orientierung von 540 Einzelkörnern mit Hilfe eines vierachsigen Röntgen-U-Tisches bestimmt. Die statistische Auswertung führt zu schwach ausgeprägten Maxima der Pole der vierzähligen Achsen und zeigt, daß die {100}-Flächenlagen merklich häufiger als rein statistisch in den drei annähernd senkrecht aufeinander stehenden makroskopischen TeilungsflächenL, S undQ liegen. — Für eine allgemeinere genetische Erklärung eines natürlichen Halit-Gefüges wären noch weitere Untersuchungen notwendig.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 418 (1975), S. 259-262 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Transsilylation Reaction with Di-tert-butyl(trimethylsilyl)phosphineDi-tert-butyl(trimethylsilyl)phosphine reacts with Dichlordimethylsilane, Trichlor(methyl)silane and silicon tetrachloride with elimination of Chlortrimethylsilane and formation of the new Silylphosphines [( CH3)3C]2PSi(CH3)3-nCln (n = 1, 2, 3). Only the compounds with n = 2 and 3 can be isolated in a pure state. The ir, raman, 1H-n.m.r. and 31P-n.m.r. spectroscopic data of the new compounds are discussed.
    Notes: Di-tert-butyl(trimethylsilyl)phosphin reagiert mit Dichlordimethylsilan, Trichlor(methyl)silan sowie mit Siliciumtetrachlorid unter Freisetzung von Chlortrimethylsilan und Bildung der neuen Silylphosphine [(CH3)3C]2PSi(CH3)3-nCln (n = 1, 2, 3), wobei nur die Derivate mit n = 2 und 3 rein isoliert werden können. Die IR-, Raman-, 1H-NMR- und 31P-NMR- spektroskopischen Daten der neuen Verbindungen werden diskutiert.
    Additional Material: 2 Tab.
    Type of Medium: Electronic Resource
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  • 10
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Organometal Phosphine Substituted Transition Metal Complexes. XXV. Organoelement(IVb) Phosphine Derivatives of Tetracarbonyl(trimethyltin)cobaltTetracarbonyl(trimethyltin)cobalt reacts with di(tert-butyl)phosphine, tri(tert-butyl)phosphine, di(tert-butyl)chlorophosphine as well as with tris(trimethylgermanium)- and tris(trimethyltin)phosphine with displacement of one CO ligand and formation of the corresponding organoelement(IVb) phosphine substituted tricarbonyl(trimethyltin)cobalt complexes. The i.r., Raman, 1H-n.m.r., and 31P-n.m.r. spectra of the complexes are reported are reported and discussed.
    Notes: Tetracarbonyl(trimethylstannyl)cobalt reagiert mit Di(tert-butyl)phosphin, Tri(tert-butyl)phosphin, Di(tert-butyl)chlorphosphin sowie Tris(trimethylgermyl)- und Tris(trimethylstannyl)phosphin unter Abspaltung eines CO-Liganden und Bildung entsprechender organo-element(IVb)phosphin-substituierter Tricarbonyl(trimethylstannyl)cobalt-Komplexe. Die Infrarot-, Raman-, 1H-NMR- und 31P-NMR-Spektren werden mitgeteilt und diskutiert.
    Additional Material: 2 Tab.
    Type of Medium: Electronic Resource
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