ISSN:
0018-019X
Schlagwort(e):
Chemistry
;
Organic Chemistry
Quelle:
Wiley InterScience Backfile Collection 1832-2000
Thema:
Chemie und Pharmazie
Notizen:
The ionization energies of four [1,2,4,5]tetrazinodi(heteroarenes) of C2h Symmetry have been measured by PE spectroscopy. It is found that the first ionization energy is very low (6.2 eV to 6.4 eV) and rather independent of the size and/or topology of the molecules. This is explained, by comparison with the results of a simple MO treatment, as being due to strong localization of the HOMO (of Au symmetry) on the [1,2,4,5]tetrazino moiety of the molecules. The PE-spectroscopic data are shown to be in agreement with the UV/VIS-and electrochemical-oxidation data published previously.
Zusätzliches Material:
3 Ill.
Materialart:
Digitale Medien
URL:
http://dx.doi.org/10.1002/hlca.19870700702
Permalink