ISSN:
0377-0486
Keywords:
Chemistry
;
Analytical Chemistry and Spectroscopy
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Physics
Notes:
The resonance Raman spectrum of the transient thioether radical cation dimer complex |(CH3)2S|2+·, generated by electron irradiation of an aqueous solution of dimethylsulfide and recorded by optical multichannel detection, is reported. Vibrational bands at 276 cm-1 and 139 cm-1 were detected and are assigned to the stretching mode of the quasi-three-electron S—S bond and a δ(CSS) deformation mode, respectively.
Additional Material:
2 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/jrs.1250110108
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