ISSN:
0009-2940
Keywords:
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
New, C-18-Functional Derivatives of DeoxycorticosteroneThe syntheses of 21-hydroxy-18-hydromethyl-4-pregnene-3,20-dione and of its 19-nor analogue are described. As a key step the known procedure for C-18 functionalization by radical-induced transfer of a C-20 nitrile group is modified and improved.
Notes:
Die Synthesen von 21-Hydroxy-18-hydroxymethyl-4-pregnen-3,20-dion und des entsprechenden 19-Nor-Analogen werden beschrieben, wobei als Schlüsselschritt ein verbessertes Verfahren zur radikal-induzierten Nitrilübertragung von C-20 nach C-18 zur Anwendung kommt.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19801130329
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