ISSN:
1618-2650
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Summary Two procedures for the photometric determination of copper as the diethyldithiocarbamate complex have been investigated as to their selectivity. In the first procedure—extraction by chloroform from a citrate solution ofph about 8.5, containing EDTA—the following elements interfere: HgII, Ag, Au, Pt, Pd, Os, SbIII, TeIV, TlIII and Bi. Interference by HgII, Ag, Pd, SbIII, TeIV and TlIII can be prevented by simple measures. In the second procedure—extraction by a solution of lead diethyldithiocarbamate in chloroform from ammoniacal citrate-only Ag, TlIII, Bi and HgII interfere. Interference by the first three elements can be prevented easily, leaving as the only serious interference in this method mercury in amounts above 500 Μg.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00463106
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