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  • 1
    ISSN: 1572-879X
    Keywords: solid base ; KNH2 loaded on alumina ; Si-C bond formation ; toluene ; diethylsilane
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract The catalytic substitution at silicon occurs in the reaction of toluene and diethylsilane in the presence of KNH2 loaded on alumina, the yield of benzyldiethylsilane being 85% in 40 h at 329 K. Benzene also reacted with diethylsilane in the presence of the catalyst to afford a 7.5% yield of benzyl diethylsilane in 20 h at 329 K.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1614-7456
    Keywords: Quadrupedal locomotion ; Gait pattern ; Adaptation ; Periodic perturbation ; Coupled oscillators ; Limb dynamics
    Source: Springer Online Journal Archives 1860-2000
    Topics: Computer Science
    Notes: Abstract Quadrupeds can acquire new gait patterns with respect to environmental changes. Yanagihara et al. have demonstrated this adaptability by experiments on a decerebrate cat. These experiments indicate that quadrupeds gradually adapt to their environment by repeating locomotion in a steady environment, and that the acquired gait pattern is persistently memorized after the locomotion. Our research aims at formulating a mathematical model of these cats' behavior and constructing a quadrupedal walking robot to realize such adaptive behavior. To date, we have proposed a mathematical description of adaptation at the level of gait pattern generation using neural oscillators. In this paper, we extend it to take into account limb dynamics. We study how to design the interaction of the oscillator and limb dynamics.
    Type of Medium: Electronic Resource
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  • 3
    ISSN: 1435-1536
    Keywords: Sequentialpolydepsipeptide ; polymericmicrosphere ; poly(L-alanyl-L-alanyl-γ-ethyl L-glutamyl-L-lactyl) ; solventevaporationprocess ; drugdeliverysystem ; malerat ; ratprostate ; 17Β estradiol
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract A sequential polydepsipeptide containing a tripeptide sequence L-alanyl-Lalanylγ-ethyl L-glutamyl and anα-hydroxy acid L-lactic acid, poly(Ala-Ala-Glu(OEt)-Lac), was synthesized to prepare the microspherical particles by the solvent evaporation process. In this case, the solvents play the most important role for the preparation of polydepsipeptide microspheres and, as an example, when 200 mg of the polydepsipeptide dissolved in 10 ml of 98/2% chloroform/dichloroacetic acid mixture was stirred at 400 rpm and 30
    Type of Medium: Electronic Resource
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