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  • 42.65.Dr  (4)
  • 33.70.Jg  (1)
  • Boundedness  (1)
  • 1
    ISSN: 1432-0649
    Keywords: 42.65.Dr ; 33.20.Fb
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract The theory of Interferometric Coherent Raman Scattering (ICRS) using “twin” broadband fields has recently been extended to include both resonant and nonresonant contributions to the signal. It is reviewed here. Valid for both ICARS and ICSRS, it is applied to new ICARS experiments on neat toluene and on alcoholic solutions of a methine dye. In each case the damped Rabi Detuning Oscillations (RDO), that are characteristic of ICRS, lead directly to vibrational frequencies and their dephasing times. The theory is also applied as a new way to determine the ratio of the nonresonant to resonant hyperpolarizabilities, accurately for toluene, and approximately for the methine dye solution whose (vibrationally) “nonresonant” contribution is negative.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1432-0649
    Keywords: 33.20.Fb ; 42.65.Dr
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract Molecules in the excited singlet and triplet state and photoproducts occuring after photoisomerization or proton transfer are investigated by time-resolved resonance Raman and resonance CARS spectroscopy with nanosecond time resolution. From the time-resolved spectra information on structures and bond strengths of these short-lived species and on their kinetics are obtained.
    Type of Medium: Electronic Resource
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  • 3
    ISSN: 1432-0649
    Keywords: 42.65.An ; 42.65.Dr ; 42.70.Jk
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract The dispersion of the third-order susceptibility of the cyanine dye bis-(dimethylamino)-heptamethinium chloride was measured by Coherent Anti-Stokes Raman Scattering (CARS) over a wide wavelength range from 530 to 830 nm. Large negative values of the real part of the second-order hyperpolarizability are observed. The data are analyzed with the help of theoretical calculations based on a perturbative approach for the nonlinearities. The dispersion behavior of the third-order susceptibility is governed by the resonant enhancement due to vibrational transitions of the first excited electronic state and, to lesser extent, by an electronic two-photon resonance around 600 nm.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Springer
    Applied physics 63 (1996), S. 209-223 
    ISSN: 1432-0649
    Keywords: 42.65.Dr ; 78.47. + p ; 42.50.Md ; 33.70.Jg
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract Applications of incoherent light techniques to time-resolved studies in condensed matter are reviewed. Vibrational dephasing ofβ-carotene and a heptamethine dye was studied by interferometric coherent anti-Stokes Raman scattering in solution revealing dephasing times between 300 fs and 1.1 ps. This technique gives results that are analogos to spectral methods, but vibrational frequencies can be determined more precisely. Electronic dephasing was studied for a variety of dyes. Forced light scattering is used to measure the initial evolution of the lineshape functiong(t) up to about 50 fs. In the lowest order approximation,g(t) =Δ 2 t 2 /2,, the dephasing is characterized by a modulation strengthΔ = 25 to 150 THz depending on the dye, the solvent and its temperature, and the pump laser wavelength. Interestingly, the modulation decreases for heptamethine in the long-wavelength tail of the absorption band. Brillouin scattering gives rise to finite dephasing times of neat solvents in forced light scattering.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    International Journal for Numerical Methods in Fluids 8 (1988), S. 617-641 
    ISSN: 0271-2091
    Keywords: Higher order ; Boundedness ; Convective transport ; Curvature ; Finite difference ; Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The paper describes a new approach to approximating the convection term found in typical steady-state transport equations. A polynomial-based discretization scheme is constructed around a technique called ‘curvature compensation’; the resultant curvature-compensated convective transport approximation is essentially third-order accurate in regions of the solution domain where the concept of order is meaningful. In addition, in linear scalar transport problems it preserves the boundedness of solutions. Sharp changes in gradient in the dependent variable are handled particularly well. But above all, the scheme, when used in conjunction with an ADI pentadiagonal solver, is easy to implement with relatively low computational cost, representing an effective algorithm for the simulation of multi-dimensional fluid flows. Two linear test problems, for the case of transport by pure convection, are employed in order to assess the merit of the method.
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
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