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  • 4-Tetramethylcyclopent-3-enyl)ethanal; Structure-odour relationship; Synthetic sandalwood odour compounds; Brahmanol type compounds.  (1)
  • Campholenic derivatives  (1)
  • 1
    Electronic Resource
    Electronic Resource
    Synthese und Geruchseigenschaften von Apo- und Homocampholenverbindungen (1998)
    Springer
    Monatshefte für Chemie 129 (1998), S. 89-97 
    Details
    ISSN: 1434-4475
    Keywords: Keywords. Sandalwood odour; Apocampholenic aldehyde; 2-(2 ; 2 ; 3 ; 4-Tetramethylcyclopent-3-enyl)ethanal; Structure-odour relationship; Synthetic sandalwood odour compounds; Brahmanol type compounds.
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary.  New substances of the brahmanol® type with special substitution at the five-membered ring are included in the study of the relationship between structure and odour of sandalwood fragrances. Apobrahmanol compounds 14 and 17 are obtained from myrtenal via apocampholenic aldehyde (12) and exert sandalwood odour. The homobrahmanol derivatives 10 and 11, synthesized from α-pinene via fencholenic aldehyde (1b), lack any sandalwood odour, although their structure is similar to other sandalwood odour compounds.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/PL00010108
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  • 2
    Electronic Resource
    Electronic Resource
    Synthese, Struktur und Reaktionen von α-Campholenepoxiden (1993)
    Weinheim : Wiley-Blackwell
    Liebigs Annalen 1993 (1993), S. 987-991 
    Details
    ISSN: 0170-2041
    Keywords: Sandalwood odour ; Epoxidation, stereocontrolled ; Campholenic derivatives ; Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Synthesis, Structure and Reactions of α-Campholenic EpoxidesThe epoxidation of α-campholenic compounds 3, 4 is described, besides the rearrangement of the epoxides 5 and 6 into the hydroxy-β-campholenic system 7, 8, the reduction to the tertiary alcohols 11a, 12a, the alkylation reaction to 11b and 12b and the conversion of 7 into the diketone 10 are reported. The stereochemistry and the odour of the new compounds are also described.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/jlac.1993199301157
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    Paper (German National Licenses)
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