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  • 1
    ISSN: 1572-8838
    Keywords: ruthenium oxide ; titanium oxide ; chlorine ; oxygen ; DEMS ; porous electrode
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Electrical Engineering, Measurement and Control Technology
    Notes: Abstract Chlorine and oxygen evolving at RuO2/Ti and RuO2–TiO2/Ti anodes have been simultaneously determined at electrode potentials from 1.0 to about 2V (vs Ag/AgCl) by differential electrochemical mass spectroscopy (DEMS). On the RuO2/Ti anodes, the threshold electrode potential for oxygen evolution increased with a decrease in RuO2 loading, while the chlorine evolution potential was unchanged. Low RuO2 loading anodes gave a high chlorine evolution ratio under various constant electrolysis potentials. On the RuO2–TiO2/Ti anodes, the threshold electrode potential for oxygen evolution increased with an increase in the TiO2 content more remarkably than that for chlorine evolution. High TiO2 content anodes gave a high chlorine evolution ratio at various constant electrolysis potentials. The combination of RuO2 and TiO2 exhibits a remarkable effect with respect to the enhancement of chlorine evolution selectivity.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1435-1536
    Keywords: Neutron Scattering ; Small-angle Scattering ; Al-Zn Alloys ; Guinier-Preston zone ; Age-hardening
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Zusammenfassung Die Kleinwinkelstreuung der Neutronen von A1-6.8 at % Zn und Al-6.8 at % Zn- 0.1 at % Mg-Legierungen während der Guinier-Preston-Zonen-Bildung wurde am KUR (Kyoto Universität Reaktor) gemessen. Die Proben wurden aus 300 °C in Salzwasser von — 20 °C abgeschreckt und bei 77 K gehalten. Sie wurden bei 40 °C während der verschiedenen Zeitdauer von 0 bis 1000 Minuten mit der nachfolgenden Neutronenmessung bei 77 K gealtert. Die gemessene zeitliche Entwicklung des Streuquerschnittes kann qualitativ erklärt werden in übereinstimmung mit Saitos Formel, die aus zwei verschiedenen Teilen besteht, die der inkohärenten anomalen Schwankung und der kohärenten geordneten Struktur der Konzentration entsprechen.
    Notes: Summary Small-angle neutron scattering from A1-6.8 at % Zn and Al-6.8 at % Zn-0.1 at % Mg alloys during Guinier-Preston zone formation have been measured at KUR (Kyoto University Reactor). The samples were quenched from 300 °C into brine at -20 °C and kept at 77 K. They were aged at 40 °C for various periods ranging from 0 up to 1000 minutes each with subsequent neutron measurement at 77 K. The observed temporal evolution of the cross section can be interpreted qualitatively in terms of Saito's formula which consists of two distinct parts due to the incoherent anomalous fluctuation and to the coherent ordered structure of the concentration.
    Type of Medium: Electronic Resource
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