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  • Analytical Chemistry and Spectroscopy  (2)
  • Engineering  (2)
  • Engineering General  (2)
  • 1
    Electronic Resource
    Electronic Resource
    Comprehensive major and trace element analysis of geological material by x-ray fluorescence, using low dilution fusions (1982)
    New York, NY [u.a.] : Wiley-Blackwell
    X-Ray Spectrometry 11 (1982), S. 55-63 
    Details
    ISSN: 0049-8246
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Physics
    Notes: A rapid method of routine whole rock analyses of major and trace elements, using low dilution fusions, is described. The method is particularly suited to use with automated x-ray fluorescence equipment, and is effective for rocks which range widely in composition. Corrections for matrix effects based on a matrix of influence coefficients, the calculation of a mass absorption coefficient from major component data and Compton scatter methods are discussed; data are presented which demonstrate that all three procedures can be used with low dilution fusions. Spectral impurities (principally of Cu, Ni and Zn) which cause problems in some trace element analyses using low dilution fusions and may also affect pressed rock powder studies are investigated and a simplified correction procedure is proposed. Lower limits of detection, accuracy and precision for determinations of 20 elements, carried out using low dilution fusions, indicate that the low dilution fusion procedure is well suited to routine whole rock analyses of major and trace elements.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/xrs.1300110206
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    Paper (German National Licenses)
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  • 2
    Electronic Resource
    Electronic Resource
    Mass spectra of complexes of 8-quinolinol with trivalent metals (AL, Ga, In, Sc, Cr and Fe) (1971)
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 5 (1971), S. 1169-1178 
    Details
    ISSN: 0030-493X
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The main fragmentation of the compounds MX3-noxn (oxH=8-quinolinol. n = 3; M=AL, Ga, In, Sc, Cr or Fe. n = 2; M=In or Fe; X=Cl or Br. InIox2. n = 1; M=AL, In or Fe; X= Cl or Br) involves loss of X and intact ox. radicals. The comparative abundances of the fragments are primarily related to the common oxidation states of the metals. For example, all the Mox3 compounds show the ions [Mox3]+ and [Mox2]+. The ions [Mox]+ and [M]+ are present when M=Ga, In, Cr or Fe but for the elements with only one oxidation state (Al or Sc) [M]+ is absent and [Mox]+ has only very low abundance. When M= Cr or Fe metal-containing ions arising from loss of species such as CO, H2O, HX, C2H2, H and OH by fragmentation of the ox ligand are also present; this behaviour is rationalised in terms of the ability of these metals to undergo a unit change in oxidation state. When n=1 the ions [MXox2]+ and [Mox2]+ and when n= 2 the ions [MX2ox]+ and [Mox3]+ are present; these ions arise by ionization and fragmentation of species formed by redistribution reactions in the mass spectrometer.
    Additional Material: 7 Tab.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/oms.1210051005
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    Paper (German National Licenses)
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  • 3
    Electronic Resource
    Electronic Resource
    The cause and cure (?) of the spurious pressures generated by certain FEM solutions of the incompressible Navier-Stokes equations: Part 1 (1981)
    Chichester : Wiley-Blackwell
    International Journal for Numerical Methods in Fluids 1 (1981), S. 17-43 
    Details
    ISSN: 0271-2091
    Keywords: Finite Element ; Navier-Stokes ; Incompressible Flows ; Penalty Methods ; Pressure Filters ; Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The spurious pressures and ostensibly acceptable velocities which sometimes result from certain FEM approximate solutions of the incompressible Navier-Stokes equations are explained in detail. The concept of pressure modes, physical and spurious, pure and impure, is introduced and their effects on discretized solutions is analysed, in the context of both mixed interpolation and penalty approaches. Pressure filtering schemes, which are capable of recovering useful pressures from otherwise polluted numerical results, are developed for two particular elements in two-dimensions and one element in three-dimensions. Implications regarding the effect of spurious pressure modes on accuracy and ultimate convergence with mesh refinement are discussed and a list of unanswered questions presented. Sufficient numerical examples are discussed to corroborate the theory presented herein.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/fld.1650010104
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    Paper (German National Licenses)
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  • 4
    Electronic Resource
    Electronic Resource
    The cause and cure (!) of the spurious pressures generated by certain fem solutions of the incompressible Navier-Stokes equations: Part 2 (1981)
    Chichester : Wiley-Blackwell
    International Journal for Numerical Methods in Fluids 1 (1981), S. 171-204 
    Details
    ISSN: 0271-2091
    Keywords: Finite Element ; Navier-Stokes ; Incompressible Flows ; Penalty Methods ; Pressure Filters ; Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: The spurious pressures and ostensibly acceptable velocities which sometimes result from certain FEM approximate solutions of the incompressible Navier-Stokes equations are explained in detail. The concept of pressure modes, physical and spurious, pure and impure, is introduced and their effects on discretized solutions is analysed, in the context of mixed interpolation and penalty approaches. Pressure filtering schemes, which are capable of recovering useful pressures from otherwise polluted numerical results, are developed for two particular elements in two-dimensions and one element in three-dimensions. The automatic pressure filter associated with the penalty method is also explained. Implications regarding the effect of spurious pressure modes on accuracy and ultimate convergence with mesh refinement are discussed and a list of unanswered questions presented. Sufficient numerical examples are discussed to corroborate the theory presented herein.
    Additional Material: 19 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/fld.1650010206
    Library Location Call Number Volume/Issue/Year Availability
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    Paper (German National Licenses)
    Fulltext
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