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  • Polymer and Materials Science  (16)
  • Caustics  (1)
  • 1
    Digitale Medien
    Digitale Medien
    Springer
    Colloid & polymer science 261 (1983), S. 825-833 
    ISSN: 1435-1536
    Schlagwort(e): Polymers ; Slow-brittle-fracture ; Toughness ; Caustics
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Maschinenbau
    Notizen: Abstract A slow crack growth was achieved in initially edge-cracked specimens made of a high-molecular weight PMMA by regulating the cross-head speed of loading by a computer-driven testing machine. The strain rate $$\dot \varepsilon $$ used during the tests varied between $$\dot \varepsilon $$ =1× l0−6 s−1 and 1×10−4 s−1. It was shown that, in this zone of slow quasi-static loading of brittle polymethylmethacrylate specimens under conditions of plane stress, the crack initiated for a critical value of loading, at some characteristic zone of strain-rate variation at the crack tip. It was established that for strain rate between $$\dot \varepsilon $$ =0.18×10−5 s−1 and $$\dot \varepsilon $$ =0.45×10−4 s−1 brittle cracks were propagating always slowly with velocities in the range ofc=3 to 5×10−2 m/s. For values ofv s outside this transition zone fracture was typically brittle with high crack-propagation velocities. As the strain rate was varying beyond the stable low-velocity region, a two-step crack velocity pattern was operative, where the one step took always low values, and the other step corresponded to crack-propagation velocities significantly higher than these limits, tending to typical brittle-fracture velocities of the material. Oscillations of the velocityc at the transition zones, or, in many cases all over the zone of slow propagation of the crack, indicated the unstable character of crack propagation, influenced by different stress raisers and especially by the opposite longitudinal boundary of the specimen. Stress intensity factor values during crack propagation, evaluated from the front (cuspoid) and the rear (external) caustic, which remained alwaysk g-dominant, were following similar trends as the variation of the crack propagation velocity.
    Materialart: Digitale Medien
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  • 2
    Digitale Medien
    Digitale Medien
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 27 (1982), S. 3019-3025 
    ISSN: 0021-8995
    Schlagwort(e): Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: The thermomechanical behavior of particle composites was investigated in their transition region. In particular, the value of the glass-transition temperature Tg, which constitutes an upper limit for the structurally important glassy region, was examined. According to experimental evidence existing in the literature the introduction of a reinforcing filler in a polymeric matrix causes Tg of the latter to increase, unless mechanical imperfections counterbalance the reinforcing effect or even produce a Tg for the composite which is lower than that of the matrix. Based on mechanical theories, valid for the mechanical moduli of viscoelastic particle composites, a model was introduced that explains why the glass transition of composite materials may be reduced in some cases, whereas it may be increased in others. The concept of interphase between inclusions and matrix was used for the development of the model. Interphase is assumed to be a region, which is created between the matrix material and the filler particles, both considered as homogeneous and isotropic, whose thermomechanical properties and volume fraction may be determined from the overall thermomechanical behavior of the composite.
    Zusätzliches Material: 2 Ill.
    Materialart: Digitale Medien
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  • 3
    Digitale Medien
    Digitale Medien
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 28 (1983), S. 3641-3649 
    ISSN: 0021-8995
    Schlagwort(e): Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Retardation spectra, derived from dynamic measurements of extension compliances along three decades on the logarithmic scale of frequencies in standard specimens prepared from a fiber-reinforced composite with their fibers parallel to the longitudinal axis of the specimens, have revealed the structure of the matrix material of the composite. The experimental results were used to prove that the physicochemical rearrangements in the vicinity of the inclusions, consisting of restrained development of the macromolecules and especially their side chains due to the presence of the other phase, concentration of voids and dirt, shrinkage stresses developed during curing and creating microcracks (radial as well as along the interface), are activated by the existence of high stress gradients and eventually stress singularities due to the strong adhesion developed between phases.
    Zusätzliches Material: 5 Ill.
    Materialart: Digitale Medien
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  • 4
    Digitale Medien
    Digitale Medien
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 30 (1985), S. 621-645 
    ISSN: 0021-8995
    Schlagwort(e): Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: The adhesion between matrix and inclusions (fibers or particulates) in a composite material is one of principal factors characterizing the mechanical and physical behavior of the modern composite materials. All theoretical models describing these substances neglect to consider the influence of the boundary layer developed between phases during the preparation of the composite. In this paper, two versions of a theoretical model were introduced for the evaluation of this mesophase layer. It had been shown that this thin layer influences considerably the physical properties of the composite. It was assumed that the physical properties of the mesophase unfold from those of the hard-core fibers to those of the softer matrix. Thus, a multicylinder model was assumed, improving the classical two-cylinder model introduced by Hashin and Rosen for the representative volume element of the composite. Based on thermodynamic phenomena appearing at the glass transition temperatures of the composite and concerning the positions and the sizes of the heat-capacity jumps there, as well as on the experimental values of the longitudinal elastic modulus of the composite, the extent of the mesophase and the mechanical properties of the composite may be accurately evaluated. These versions of model are based on a previous one concerning a multilayer model, but they are considerably improved, in order to take into consideration, in a realistic manner, the physical phenomena developed in fiber-reinforced composites.
    Zusätzliches Material: 8 Ill.
    Materialart: Digitale Medien
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  • 5
    Digitale Medien
    Digitale Medien
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 25 (1987), S. 1285-1294 
    ISSN: 0887-624X
    Schlagwort(e): Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie
    Notizen: Structural changes which take place in many amorphous polymers, when they are annealed at temperatures near the glass transition temperature, have important theoretical, physical, and mechanical consequences. In this paper the possible existence of some local ordering in highlycrosslinked epoxy resins is studied. Three kinds of tests - TMA, DSC, and dynamic experiments - are used for a type of epoxy resin, cured with six different amounts of curing agent. In order to study the effect of the thermal history on the behavior of the polymer at its transition region, as well as the morphology of the materials tested, three different thermal treatments have been followed. Interesting results were derived concerning the influence of these parameters to these parameters to the mechanical characterization of the polymer.
    Zusätzliches Material: 9 Ill.
    Materialart: Digitale Medien
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  • 6
    Digitale Medien
    Digitale Medien
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 42 (1991), S. 3059-3063 
    ISSN: 0021-8995
    Schlagwort(e): Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Four polystyrene-polyurethane mechanical blends were prepared with 5, 10, 20, and 40% thermoplastic polyurethane, respectively. Their impact properties were compared with pure polystyrene and commerical types of impact polystyrene. The rheological properties of the blends were studied with DSC and dynamic mechanical spectroscopy. It was found that addition of softer polyurethane conglomerates embedded inside the polystyrene matrix, although increasing the toughness of the blend as expected from addition of the softer particulate, also increased the glassy region of the blends by shifting their Tgs to higher temperatures. A theory based on the interaction of phases was propounded explaining this phenomenon.
    Zusätzliches Material: 3 Ill.
    Materialart: Digitale Medien
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  • 7
    Digitale Medien
    Digitale Medien
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 20 (1976), S. 903-910 
    ISSN: 0021-8995
    Schlagwort(e): Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: A class of amine-cured epoxy resins containing various amounts of polysulfide plasticizer were subjected to dynamic testing during curing at high temperature. Both E modulus and loss factor were determined simultaneously. It was proved that the method allowed for rapid determination of the general pattern of the crosslinking procedure and the necessary curing time and, in general, that dynamic methods are most suitable for the mechanical characterization of polymers under curing at each stage of the curing cycle.
    Zusätzliches Material: 4 Ill.
    Materialart: Digitale Medien
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  • 8
    Digitale Medien
    Digitale Medien
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 28 (1983), S. 3145-3153 
    ISSN: 0021-8995
    Schlagwort(e): Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: The influence of moisture absorption on the extent of the boundary interphase in particulate composites is thoroughly studied. It was found that, during the process of moisture absorption there is a variation of the extent of the boundary interphase, closely related to the degradation of the mechanical behavior of the composite, as well as to the percentage amount of moisture absorbed. An explanation of the observed relationship was advanced, based on a theoretical mechanism of absorption. This study complements a previous one, where the observed degradation of the thermomechanical properties of particulate composites due to moisture absorption was shown to be intimately interrelated with the state and extent of the interphase between fillers and matrix.
    Zusätzliches Material: 6 Ill.
    Materialart: Digitale Medien
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  • 9
    Digitale Medien
    Digitale Medien
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 21 (1977), S. 689-701 
    ISSN: 0021-8995
    Schlagwort(e): Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: Thermal expansion coefficients and glass transition temperatures for metal-epoxy composites were determined experimentally. Results were in fair agreement with existing theories when certain fundamental assumptions were fulfilled. The effects of filler content and particle size as well as of adhesion between matrix and filler particles were investigated. The latter, in particular, was found to be of cardinal importance for the properties examined in the present work.
    Zusätzliches Material: 11 Ill.
    Materialart: Digitale Medien
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  • 10
    Digitale Medien
    Digitale Medien
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 22 (1978), S. 1417-1430 
    ISSN: 0021-8995
    Schlagwort(e): Chemistry ; Polymer and Materials Science
    Quelle: Wiley InterScience Backfile Collection 1832-2000
    Thema: Chemie und Pharmazie , Maschinenbau , Physik
    Notizen: A class of plasticized epoxy polymers were subjected to indentation tests over a wide range of temperature and plasticizer percentage. Constant or continuously varying temperature tests were carried out under constant load, and the materials exhibited creep behavior according to the temperature and the amount of plasticizer. Thermal expansion properties were also studied, and glass transition temperature as well as thermal expansion coefficients a1 and a2 were determined for each individual material. Theoretical predictions were found valid under the present conditions.
    Zusätzliches Material: 7 Ill.
    Materialart: Digitale Medien
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