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  • 1
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 13 (1971), S. 353-369 
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Kinetic data of the reaction between sulphite ions and dissolved oxygen depend on the purity of sulphite used. Thus it is adequate to determine them for each batch and concentration of sulphite used. Besides the dependence of reaction rate constants on catalyst concentration, it is usually also required to know their dependence on pH and on temperature. Both quantities can change to a great extent especially in absorption apparatus in which high sulphite conversion occurs. They profoundly influence the value of the reaction rate constant. To get a complete picture of the influence of these three quantities without repeating extensive kinetic measurements for every kind and concentration of sulphite used, a method for obtaining information on the influence of all three quoted quantities in the range of values of interest for application is presented.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 16 (1974), S. 1135-1137 
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 21 (1979), S. 907-908 
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 19 (1977), S. 741-748 
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 23 (1981), S. 301-319 
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: It has been shown both theoretically and experimentally that interphase nitrogen transport may have a significant influence on the rate of interphase oxygen transport, and thereby also on the value of the volumetric mass transfer coefficient of oxygen, kla, determined in mechanically agitated bubble fermentors using the variants of dynamic method presented in the literature. The experiments were carried out in 1M KCI solution at five stirrer frequencies and two gas inlet levels. The gas interchanges were performed either without interrupting the aeration and agitation of the charge (A) or with the aeration and agitation of the charge turned on at the same time (B). The applied variants of the interchange were N2→ O2→, O2→ N2, N2→ air, air→ N2, O→ O2, and O→ air. In the two last variants the oxygen dissolved in the charge was removed by reacting with sulfite ions. The kla values calculated by allowing for the nitrogen transport for procedure A were approximately equal to the values obtained by disregarding the nitrogen transport, whereas those for procedure B were higher (up to 40%), than the values obtained disregarding the nitrogen transport.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 23 (1981), S. 1467-1484 
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A steady-state method for kla determination has been presented using the Michaelis-Menten two-substrate kinetic equation for oxidation of glucose in the presence of the enzymes glucose oxidase and excess catalase. The conditions have been specified where spontaneous hydrolysis of lactone is sufficiently rapid, thus eliminating inhibitory action of lactone on the oxidation. In glucose oxidase-free batches, the kla values were determined using various modification of the dynamic method. The dynamic methods in which gas interchange was effected without interrupting aeration and agitation of the batch yielded erroneously lower kla values as compared to the results of steady-state methods if the measured kla value was higher than 0.03 s-1. The values yielded by the dynamic method in which the gas interchange was effected at the same time with turning on aeration and agitation of the batch agreed with values resulting from the steady-state method provided that the measured kla values were lower than 0.08-1 and the simultaneous interfacial transport of nitrogen and oxygen had been taken into account in the evaluation. At kla values higher than 0.08 -1, this modification of the dynamic method also yielded lower kla values as compared with the outcome of the steady-state method. The experiments performed do not, however, allow one to decide unambiguously on the whether these lower kla values are due to failure of the adopted model to describe adequately the dynamic behavior of the system or whether they are true values differing from those yielded by the steady-state method on account of different physical properties of compared batches.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 25 (1983), S. 1401-1418 
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A general model of the transient behaviour of an oxygen probe is derived on more general assumptions than those previously considered. The present state of the art is shorly discussed in its relation to the newly derived equations: (1) the reducibility of the three-layer diffusional model to two-layer ones is discussed, and the two-layer model considering the membrane and the liquid film is verified experimentally, (2) experimental and theoretical treatments of transient probe characteristics determination are examined, and (3) the influence of chemical reactions of the first order as well as of zero order (microorgaganism respiration) in measured media on transientd probe characteristics is quantified.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 33 (1989), S. 39-48 
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Various experimental procedures for the determination of transient characteristics with significant liquid film effects were tested. A comparison between transient characteristics obtained experimentally and those calculated from rational models indicates that all procedures but one give highly inconsistent results. Recalculation of transient characteristics with no liquid film (easily measured in the gas phase) to that with liquid film (occurring in viscous liquids) is recommended as well as the selected experimental procedure which yields consistent results in the situations where the steady-state probe reading is decreased up to one-half due to the liquid film.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Biotechnology and Bioengineering 32 (1988), S. 482-490 
    ISSN: 0006-3592
    Keywords: Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Empirical equations used so for for computing kla in mechanically agitated aerated vessels agree well with the measured dependence of Kla on the power input of the stirrer and the superficial velocity of the gas. However, they do not fit the dependence of Kla on the physical properties of the liquid batch. From the data published so far it can be deduced that the equations suitable for the description of the dependence of kmola on the liquid physical properties must include some independent variable, which characterizes the rate of coalescence of the bubbles. About 400 experimental values of Kla were compared with those calculated from different relations. This comparison shows that the rate of coalescence for the aqueous electrolyte solutions is well described on the basis of the Gibbs theory of adsorption of the solute in the surface layer of the solution.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
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  • 10
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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