ISSN:
1572-879X
Keywords:
solid base
;
KNH2 loaded on alumina
;
Si-C bond formation
;
toluene
;
diethylsilane
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract The catalytic substitution at silicon occurs in the reaction of toluene and diethylsilane in the presence of KNH2 loaded on alumina, the yield of benzyldiethylsilane being 85% in 40 h at 329 K. Benzene also reacted with diethylsilane in the presence of the catalyst to afford a 7.5% yield of benzyl diethylsilane in 20 h at 329 K.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1023/A:1019006816637
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