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  • PACS: 42.60.B; 35.80.+  (2)
  • PACS. 21.10.Ky Electromagnetic moments - 31.30.Gs Hyperfine interactions and isotope effects, Jahn-Teller effect - 32.10.Fn Fine and hyperfine structure  (1)
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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Applied physics 64 (1997), S. 521-524 
    ISSN: 1432-0649
    Keywords: PACS: 42.60.B; 35.80.+
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: 2 and two diode lasers as pump sources and experiments with this setup are presented. In contrast to the majority of known applications of the difference frequency mixing with solid state or gas lasers, we apply two single mode diode lasers with emission wavelengths of 690 nm and 805 nm, respectively. By fixing the emission wavelength of one diode laser and tuning the wavelength of the second laser, by changing temperature or excitation current, we can cover typically 0.87 cm-1 (FWHM) in good agreement with recently published data and theory. With an input power of 20 mW and 6 mW we achieved an output power in the nW-range. To demonstrate the capabilities of the spectrometer we scanned CO and OCS absorption lines near 2107 cm-1. From these experiments we deduce an overall signal-to-noise ratio of 1000:1 and a spectral resolution better than 30 MHz. With such parameters a trace gas detection of CO at sub-ppm level will be possible.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1432-0649
    Keywords: PACS: 42.60.B; 35.80.+
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: 2 and two diode lasers as pump sources are presented. A single-mode Fabry–Pérot-type tunable diode laser (TDL) and an external-cavity diode laser (ECL) were combined to generate radiation in the mid-infrared region near 7.2 μm. With a TDL at a wavelength of approximately 1290 nm and an ECL emitting between 1504 and 1589 nm it was possible to carry out spectroscopic experiments concerning SO2 at five different phasematching points between 1350 and 1400 cm-1 by fixing the wavelength of one pump laser and tuning the wavelength of the other. With an input power of 8 mW for the single-mode Fabry–Pérot-type diode laser and 6 mW for the external-cavity laser an output power of about 10 nW was generated. Using the tuning capabilities of the external-cavity laser a spectral region up to 5 cm-1 could be covered within one scan. Measurements of SO2 absorption lines at low pressure demonstrate the high-resolution features of the spectrometer. Moreover, these data provide new direct experimental phasematching data for the rarely investigated spectral region at 7.2 μm.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    The European physical journal 11 (2000), S. 197-205 
    ISSN: 1434-6079
    Keywords: PACS. 21.10.Ky Electromagnetic moments - 31.30.Gs Hyperfine interactions and isotope effects, Jahn-Teller effect - 32.10.Fn Fine and hyperfine structure
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract: The isotope shift (IS) and hyperfine structure (hfs) of nine levels (31720 to 38921 cm-1) assigned to the configuration 4 f 12 6 s 7 s in neutral erbium have been determined experimentally using Doppler-reduced saturation absorption spectroscopy in a gas discharge. We performed a fine structure analysis in the SL-coupling scheme of the single configuration 4 f 12 6 s 7 s, confirming and extending the classification of even parity Er I levels. We discriminated the different hfs contributions of the 4f12 core and the (6 s +7 s) outer electrons of the shell in a non-relativistic JJ-coupling approach and in the relativistic effective tensor operator formalism in SL-coupling. The relativistic one-electron parameters of the hfs for 167Er were fitted to the experimental data by a least squares fit procedure: [0pt] a 01 4f =-147(3) MHz, [0pt] a 10 6s + a 10 7s =-1840(30) MHz, [0pt] b 02 4f =6560(80) MHz. The level dependencies of the isotope shift were evaluated based on crossed second order (CSO) effects. We obtained the following results for the CSO parameters for the isotope pairs 170-168Er: d 6s7s =-740(30) MHz, z 4f = 0(5) MHz, ( g 3,6s ( f , 6 s )+ g 3, 7s ( f , 7 s ))= -24(15) MHz and for 170-166Er: d 6s7s =-1500(50) MHz, z 4f =0(10) MHz, ( g 3,6s ( f ,6 s )+ g 3,7s ( f +7 s ))=-50(29) MHz. The resulting parameters for the hfs are compared with those known for other configurations of the Er atom and ion.
    Type of Medium: Electronic Resource
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