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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    International journal of thermophysics 13 (1992), S. 575-592 
    ISSN: 1572-9567
    Keywords: hot-wire technique ; molten salt ; thermal conductivity
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract Molten salts are one of the few remaining classes of fluids for which standardquality (±1% accuracy) data on thermal conductivity have not hitherto been available. We have therefore developed a new apparatus based on the transient hot-wire technique to obtain reference-quality measurements of the thermal conductivity of molten salts at high temperatures. Liquid metal-filled quartz capillaries served as insulated hot wires in our method, and in addition, a two-wire technique was used in order to obtain absolute values of the thermal conductivity. New data for the NaNO3-KNO3 eutectic between 525 and 590 K are reported in this paper and comparisons with other recent measurements are shown.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    International journal of thermophysics 13 (1992), S. 855-871 
    ISSN: 1572-9567
    Keywords: kinetic theory ; molten salts ; thermal conductivity
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract A new model based on the rough hard-sphere theory is proposed for the correlation and prediction of the thermal conductivity of molten salts. The model is capable of predicting the thermal conductivity of all the members of a family of molten salts characterized by a common anion if the behavior of any single member of the family of salts is known. Only the molar volumes of the molten salt and the solid salt at the melting temperature are required in the calculations. In addition, the model is easily extended to mixtures with a simple mixing rule.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    International journal of thermophysics 8 (1987), S. 247-256 
    ISSN: 1572-9567
    Keywords: corresponding states ; enthalpy ; entropy ; mixtures
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract The generalized corresponding-states principle (GCSP), based on the properties of two nonspherical reference fluids, has been shown to be a powerful technique for the correlation and prediction of thermodynamic properties. In this work we show GCSP calculations of enthalpy and enropy departures for pure fluids and fluid mixtures. The mixtures studied include those conforming well to traditional corresponding states theory (e.g., n-pentane + n-octane), as well as those that have not hitherto been amenable to such treatments (e.g., n-pentane + ethanol). It is shown that the GCSP method works well for all classes of mixtures and compares favorably with other methods of prediction. The use of cubic equations of state to represent the reference fluids gives the GCSP method flexibility while maintaining accuracy in the prediction. No adjustable parameters are required in the GCSP calculations of enthalpy and entropy departures.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Springer
    International journal of thermophysics 20 (1999), S. 149-161 
    ISSN: 1572-9567
    Keywords: viscosity ; thermal conductivity ; rough-hard-sphere ; refrigerants ; refrigerant mixtures
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract Two methods are presented for the correlation and prediction of the viscosities and thermal conductivities of refrigerants R11, R12, R22, R32, R124, R125, R134a, R141b, and R152 and their mixtures. The first (termed RHS1) is a modified rough-hard-sphere method based on the smooth hard-sphere correlations of Assael et al. The method requires two or three parameters for characterizing each refrigerant but is able to correlate transport properties over wide ranges of pressure and temperature. The second method (RHS2) is also a modified rough-hard-sphere method, but based on an effective hard-sphere diameter for Lennard–Jones (LJ) fluids. The LJ parameters and the effective hard-sphere diameter required in this method are determined from a knowledge of the density–temperature behavior of the fluid at saturation. Comparisons with the rough-hard-sphere method of Assael and co-workers (RHS3) are shown. We also show that the RHS2 method can be used to correlate as well as predict the transport properties of refrigerants.
    Type of Medium: Electronic Resource
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