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  • 1
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    The @journal of physical chemistry 〈Washington, DC〉 98 (1994), S. 1306-1310 
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Industrial and engineering chemistry 20 (1981), S. 77-81 
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Industrial and engineering chemistry 18 (1979), S. 435-438 
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Springer
    International journal of thermophysics 13 (1992), S. 575-592 
    ISSN: 1572-9567
    Keywords: hot-wire technique ; molten salt ; thermal conductivity
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract Molten salts are one of the few remaining classes of fluids for which standardquality (±1% accuracy) data on thermal conductivity have not hitherto been available. We have therefore developed a new apparatus based on the transient hot-wire technique to obtain reference-quality measurements of the thermal conductivity of molten salts at high temperatures. Liquid metal-filled quartz capillaries served as insulated hot wires in our method, and in addition, a two-wire technique was used in order to obtain absolute values of the thermal conductivity. New data for the NaNO3-KNO3 eutectic between 525 and 590 K are reported in this paper and comparisons with other recent measurements are shown.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Springer
    International journal of thermophysics 13 (1992), S. 855-871 
    ISSN: 1572-9567
    Keywords: kinetic theory ; molten salts ; thermal conductivity
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract A new model based on the rough hard-sphere theory is proposed for the correlation and prediction of the thermal conductivity of molten salts. The model is capable of predicting the thermal conductivity of all the members of a family of molten salts characterized by a common anion if the behavior of any single member of the family of salts is known. Only the molar volumes of the molten salt and the solid salt at the melting temperature are required in the calculations. In addition, the model is easily extended to mixtures with a simple mixing rule.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Springer
    International journal of thermophysics 20 (1999), S. 149-161 
    ISSN: 1572-9567
    Keywords: viscosity ; thermal conductivity ; rough-hard-sphere ; refrigerants ; refrigerant mixtures
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract Two methods are presented for the correlation and prediction of the viscosities and thermal conductivities of refrigerants R11, R12, R22, R32, R124, R125, R134a, R141b, and R152 and their mixtures. The first (termed RHS1) is a modified rough-hard-sphere method based on the smooth hard-sphere correlations of Assael et al. The method requires two or three parameters for characterizing each refrigerant but is able to correlate transport properties over wide ranges of pressure and temperature. The second method (RHS2) is also a modified rough-hard-sphere method, but based on an effective hard-sphere diameter for Lennard–Jones (LJ) fluids. The LJ parameters and the effective hard-sphere diameter required in this method are determined from a knowledge of the density–temperature behavior of the fluid at saturation. Comparisons with the rough-hard-sphere method of Assael and co-workers (RHS3) are shown. We also show that the RHS2 method can be used to correlate as well as predict the transport properties of refrigerants.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Springer
    International journal of thermophysics 8 (1987), S. 247-256 
    ISSN: 1572-9567
    Keywords: corresponding states ; enthalpy ; entropy ; mixtures
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract The generalized corresponding-states principle (GCSP), based on the properties of two nonspherical reference fluids, has been shown to be a powerful technique for the correlation and prediction of thermodynamic properties. In this work we show GCSP calculations of enthalpy and enropy departures for pure fluids and fluid mixtures. The mixtures studied include those conforming well to traditional corresponding states theory (e.g., n-pentane + n-octane), as well as those that have not hitherto been amenable to such treatments (e.g., n-pentane + ethanol). It is shown that the GCSP method works well for all classes of mixtures and compares favorably with other methods of prediction. The use of cubic equations of state to represent the reference fluids gives the GCSP method flexibility while maintaining accuracy in the prediction. No adjustable parameters are required in the GCSP calculations of enthalpy and entropy departures.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Springer
    International journal of thermophysics 17 (1996), S. 23-33 
    ISSN: 1572-9567
    Keywords: equation of state ; heavy hydrocarbons ; natural gas ; supercritical carbon dioxide ; wax deposition
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract Heavy hydrocarbons are becoming an increasingly important problem for the natural gas industry as it develops more costly gas reserves, such as those in the deep Gulf of Mexico. The waxy substances precipiate during natural gas processing, causing blockage of transmission pipelines. Knowledge of the solubility behavior of these hydrocarbon solids is therefore necessary to develop solutions to the solid deposition problem. This work reports solid-supercritical fluid equilibrum data for long-chain n-alkanes in carbon dioxide, a component of natural gas, over a range of temperatures and pressures that are typical of natural gas processing. A flow apparatus was used to measure the solubility, and the data were correlated by the Patel-Teja equation of state. Satisfactory agreement was obtained between calculated and experimental values, so the equation of state may be used to estimate the conditions for solid deposition and the amounts of solids formed at typical processing conditions.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Springer
    International journal of thermophysics 17 (1996), S. 111-125 
    ISSN: 1572-9567
    Keywords: acetic arid ; aqueous mixtures ; thermal conductivity transient hot-wire technique ; transport properties ; viscosity
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract The viscosity and thermal conductivity of acetic acid water mixtures were measured over the entire composition range and at temperatures ranging from 293 to 453 K. Viscosity measurements were performed with a high-pressure viscometer and thermal conductivity was measured using a modified transient hot-wire technique. A mercury filled. glass capillary was used as the insulated hot wire in the measurements. The l iscosity data showed unusual trends with respect to composition. At it given temperature. the viscosity was seen to increase with increasing acid concentration, attain a maximum. and then decrease. The thermal conductivity, on the other hand, decreased monotonically with acid concentration. A generalized corresponding-states principle using water and acetic acid as the reference fluids was used to predict both viscosity and thermal conductivity with considerable sucres.
    Type of Medium: Electronic Resource
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  • 10
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: P-V-T-x data for the propane-perfluorocyclobutane system are reported in this paper. The data cover a temperature range from 329.4 to 397.7°K and a pressure range from 60 to 6920 kPa. The low pressure compressibility measurements were used to determine second virial coefficients of pure propane and pure perfluorocyclobutane and for seven of their mixtures. The prediction of second virial coefficients using an extended corresponding states principle is also reported. Excellent predictions of the second virial coefficients of both pure components and mixtures have been obtained using, in the case of mixtures, a binary interaction coefficient obtained from a study of the critical states of the system.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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