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  • 1
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 99 (1993), S. 6031-6051 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: The rotational motion of homonuclear diatomic molecules confined to two dimensions at finite temperatures is discussed within the framework of path-integral Monte Carlo (PIMC) techniques. For single rotators the symmetry restriction on the total wave function coupling nuclear spin and rotations of these diatomic molecules is carried over to PIMC for fermionic and bosonic diatomic molecules. Three experimentally relevant quantum statistical averages are formulated, and quantum effects due to discrete level spacing and exchange are separated with the help of these averages. The method is applied to single N2 and H2 rotators adsorbed on graphite in the frozen-in crystal field which is due to the commensurate ((square root of)3×(square root of)3)R30° "2-in'' herringbone phase. Contrary to H2, exchange effects are negligible for N2 in the relevant temperature range. The resulting sign problem for certain combinations of molecule and averaging procedure is discussed. PIMC simulations of the phase transition from the translationally (square root of)3-ordered and orientationally disordered phase to the herringbone phase were carried out for complete N2 monolayers without a symmetry restriction on the wave function. Due to dispersive quantum fluctuations, transition temperature and ground-state order parameter are depressed by roughly 10% as compared to classical MC simulations of the same realistic model. In addition, the PIMC results are compared to quasiharmonic and quasiclassical approximations. The quasiharmonic treatment yields the correct order parameter suppression, the quasiclassical simulation the lowering of the transition temperature, but only the full quantum PIMC simulations describe the entire temperature range of interest correctly.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 79 (1996), S. 5018-5020 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Cr(backward-slash)(CoPtCr,CoPt) films were deposited on oxidized Si 〈100〉 substrates via dc magnetron sputtering. Process parameters, such as deposition rates, number of bilayers, and bias voltage, were varied to achieve the hard magnetic properties without thermal processing of the films. Coercivities in the range of 2000 Oe, with corresponding squareness of about 0.8–0.9, and remanent magnetization in the range (3–3.6) memu/cm3, were achieved by identification of the optimum conditions. © 1996 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 77 (1995), S. 1952-1958 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Metalorganic molecular beam epitaxy (MOMBE) growth characteristics of GaAs using triethylgallium (TEGa) and trisdimethylaminoarsenic (TDMAAs) are studied in detail by using reflection high energy electron diffraction intensity oscillations. It is found that the GaAs growth rate variation with substrate temperature (Tsub) is similar to that in the MOMBE growth of GaAs with TEGa and elemental As (As4) except in the high Tsub region, despite the use of uncracked TDMAAs instead of As4. GaAs growth starts at about 350 °C and shows a maximum growth rate at about 500 °C. However, the absolute growth rate is about 15% lower than that using As4 with the same TEGa flow rate in the mass-transport limited growth region. Above 600 °C the growth rate shows a rapid decrease with increasing Tsub. Further, it is found that etching of GaAs occurs when only TDMAAs is supplied to the GaAs surface at Tsub above 500 °C. Unintentionally doped GaAs films show n-type conduction in the whole Tsub range investigated with the highest 77 K electron mobility of 22 000 cm2/V s and a low carrier concentration of 2×1015 cm−3 for the 650 °C grown samples. 4.2 K photoluminescence spectra show an exciton-bound-to-impurity emission peak at the wavelength of 819.3 nm with a full width at half-maximum of less than 3.5 meV indicating good optical qualities. © 1995 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 65 (1994), S. 1027-1029 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Metal-organic molecular-beam epitaxy growth of GaSb is investigated for the first time by using the new precursor trisdimethylaminoantimony (TDMASb) together with triethylgallium (TEGa). An etching effect is observed when TDMASb is supplied to the (001) GaSb surface without precracking. The etching rate is dependent on the substrate temperature and TDMASb flow rate, while independent of the TEGa flow rate. GaSb layers can be grown when the TDMASb is precracked in the gas cracker cell. The etching mechanism is discussed in connection with the decomposition process of TDMASb on the surface.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 102 (1995), S. 4538-4547 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Based on path-integral Monte Carlo simulations we investigate systematically the influence of quantum fluctuations on a model for orientational ordering. The quantum anisotropic-planar-rotor Hamiltonian with its herringbone ground state serves as our model for strictly two-dimensional, orientationally ordered linear molecules. We find several distinct regimes as the strength of the quantum fluctuations is increased: (i) a regime with renormalized transition temperature and ground state order parameter which describes systems like N2 physisorbed on graphite; (ii) crossover behavior with residual ground state order but an increased order parameter at higher temperatures; (iii) a regime characterized by vanishing ground state order but significant order in some range of higher temperatures; and (iv) a regime with orientational disorder at all temperatures. This sequence is interpreted in terms of reentrant rotational quantum melting. In addition we probe the range of validity of simple approximation schemes such as the quasiharmonic and the quadratic Feynman–Hibbs effective potential approximations. Both methods fail to describe the full scenario for large quantum fluctuations even on a qualitative level. © 1995 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Journal of food quality 15 (1992), S. 0 
    ISSN: 1745-4557
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Process Engineering, Biotechnology, Nutrition Technology
    Notes: Peaches (Prunus persica L. Batsch) were sampled during the early harvest season to determine the percentage of immature fruits harvested in commercial orchards. The results indicated that the earlier the harvest, the higher the percentage of immature fruits (24%). Six days after the harvest season started, the percentage of immature fruits stabilized to 13%. Removal of immature fruits decreased acidity, increased soluble solid/acidity ratio but did not affect soluble solids content in peach puree. Color was improved by the removal of immature fruits in the cultivar (cv) Baby Gold 5, but no effect was noted in Allgold; puree of the cv Baby Gold 7 showed an improvement in color in 1989 but no effect in 1988.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Journal of food quality 13 (1990), S. 0 
    ISSN: 1745-4557
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Process Engineering, Biotechnology, Nutrition Technology
    Notes: Chemical and sensory analyses were designed to evaluate 14 traditional wine grapes grown in Arkansas as to their suitability for varietal grape juice. Six were classified as red or pink grapes: Chancellor, Cabernet Sauvignon, Villard noir, Gewurztraminer (pink when heated), Cynthiana, and Noble, and seven were white grapes: Aurore, Cayuga, Carlos, Chardonnay, Seyval, Vidal, Verdelet and White Riesling. Concord (red) and Niagara (white), traditional juice grapes, were also included in the study. All were processed by immediately pressing, heat processing at 60°C, heat processing at 80°C, and 24 h skin contact following pressing. Juices were evaluated 1 month after processing and again after 5 months storage at 37°C. The preferred treatments for white grape juices were the immediately pressing treatment of Niagara and Aurore and the 24-h skin contact treatment of Niagara, Verdelet and Vidal. Only the flavor of Verdelet and Aurore were ranked as high as the Niagara by a trained sensory panel. Generally, a nonheat treatment was ranked highest for flavor of the red juices, with the exception of Gewurztraminer, a pink juice when heated. Except for Villard noir, all of the red juices were ranked as good or better than Concord. White cultivars were closely ranked for color, with Vidal and Chardonnay being ranked lowest after storage. Heat treatments were generally ranked higher than nonheat treatments in color for the red and pink juices. Chemical analyses of the juices indicated that all cultivars were harvested within an acceptable pH range.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Palo Alto, Calif. : Annual Reviews
    Annual Review of Phytopathology 10 (1972), S. 429-454 
    ISSN: 0066-4286
    Source: Annual Reviews Electronic Back Volume Collection 1932-2001ff
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition , Biology
    Type of Medium: Electronic Resource
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  • 9
    ISSN: 1600-0765
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Medicine
    Notes: The objective of this study was to use an in vivo model of jreiodontitis (mouse calvaria) to quantify the effects of local release of secreted human macrophage products, 17β-estradiol (E2), and proinflammatory lipopolysaccharide (LPS) on histologic bone resorption. Human THP-1 monocytes (106) were converted to macrophage phenotype by 500 ng/ml phorbol 12-myristate-13-acetate (PMA) and treated as follows: no stimulation or Escherichia coli LPS (10 µg/ml) alone or in combination with a physiologic dose of E2 (100 pg/ml) for 24 h in RPMI/10% FBS, washed extensively, then incubated for 24 h in serum-free media. Sujrenatant products were concentrated and incorporated into a 4% (w/v) methylcellulose gel. Separate gels were incorporated with the following: LPS (500 µg/animal) alone, high dose of E2 (10 ng/animal) alone, a combination of LPS+E2, or gel only (controls). Loaded or control gels were placed into a polylactic acid occlusive dome, inserted subcutaneously over the calvaria of mature ovariectomized ICR Swiss mice (8 mice×7 groups×2 times [5/14 days] = 112 animals), then calvaria were evaluated histologically. Macrophage stimulation with LPS alone, but not LPS in combination with E2, produced sujrenatants which upregulated osteoclast numbers in the suture area compared to gel controls at 5 days (p = 0.009). The addition of LPS directly to the local delivery gels significantly upregulated osteoclasts in endosteal surfaces compared to gel controls at 5 days (p = 0.024) and at 14 days (p = 0.025). The addition of E2 to LPS down-regulated resorption to a level not different from gel controls at 14 days. This in vivo model appears effective in studying inflammatory bone resorption, which may be inhibited by E2 directly or through its influence on secreted macrophage products.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    Oxford, UK : Munksgaard International Publishers
    Journal of periodontal research 38 (2003), S. 0 
    ISSN: 1600-0765
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Medicine
    Notes: Background:  Periodontitis is characterized by altered bone turnover, but local measurements are difficult.Objectives:  The objective of this study was to develop a method to measure multiple markers of bone turnover from single samples collected at various bone surfaces of the periodontium, and to test the ratios of these markers against more traditional serum and gingival crevicular fluid (GCF) samples.Materials and methods:  Fourteen subjects with untreated periodontitis were recruited for sampling serum, GCF (from sites ≥ 5 mm probing depth that bled on probing) and washes of periodontal bone surfaces (adjacent interproximal, vestibular cortical and trabecular bone) with a novel irrigating device. All samples were analyzed for osteocalcin (OC, bone turnover marker; RIA), cross-linked N-telopeptide of type I collagen (NTx, bone resorption marker; ELISA) and albumin (Alb, serum protein; ELISA). Results were reported as ratios: OC/NTx to determine relative bone turnover, and OC/Alb or NTx/Alb to determine local OC or NTx production.Results:  The OC/NTx ratio was significantly higher (p ≤ 0.05) in serum vs. GCF (OC undetectable), interproximal bone and cortical vestibular bone, but significantly lower than in trabecular vestibular bone. The OC/Alb ratio for serum was also statistically lower than for vestibular trabecular bone. The NTx/Alb ratio for serum was statistically lower than for GCF and all the bone wash test sites. The results indicated considerable local production of both OC and NTx.Conclusions:  This system demonstrated that multiple markers of bone turnover can be harvested by irrigation from periodontal bone microenvironments. Bone turnover profiles from periodontal bone surfaces and GCF differed from systemic bone turnover profiles (serum) and may be valuable in tracking site-specific responses to disease or treatment.
    Type of Medium: Electronic Resource
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