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  • 11
    Electronic Resource
    Electronic Resource
    Westerville, Ohio : American Ceramics Society
    Journal of the American Ceramic Society 82 (1999), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The results for the corrosion of alumina single crystals at 1700-2000°C in argon, argon/water vapor, air, and air/water vapor for 10 h are reported. There were no obvious weight and volume changes after corrosion. White spots were observed on the surfaces of the specimens after corrosion tests. The initial temperature for the appearance of these white spots was 1800°C for argon and air, 1900°C for argon/water vapor, and 2000°C for air/water vapor. These white spots were likely formed by internal impurities, which diffused outward to the surface and coalesced at high temperatures. There was no evidence of corrosion damage inside the specimens. The flexural strength of the specimens was clearly enhanced after the corrosion tests and showed no evident relation to the corrosion conditions. This increase in strength after corrosion was likely due to the healing of surface machining flaws. The surface flaw healing temperature for alumina crystals was higher than 1400°C.
    Type of Medium: Electronic Resource
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  • 12
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Thermogravimetry, differential thermal analysis, mass spectrometry, and X-ray diffractometry were used to study the reaction process of the in situ reaction between Si3N4, B4C, and carbon for the synthesis of silicon carbide–boron nitride composites. Atmospheres with a low partial pressure of nitrogen (for example argon + 5%–10% nitrogen) seemed to inhibit denitrification and also maintain a high reaction rate. However, the reaction rate decreased significantly in a pure nitrogen atmosphere. The experimental mass spectrometry results also revealed that B4C in the Si3N4–B4C–C system inhibited the reaction between Si3N4 and carbon and, even, the decomposition of Si3N4. The present results indicate that boron could be a composition stabilizer for ceramic materials in the Si-N-C system used at high temperature.
    Type of Medium: Electronic Resource
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  • 13
    Electronic Resource
    Electronic Resource
    Westerville, Ohio : American Ceramics Society
    Journal of the American Ceramic Society 85 (2002), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: This work proposes a new approach, based on the reaction Si3N4+ 2B2O3+ 9C → 3SiC + 4BN + 6CO, to synthesize an SiC–BN composite. The composite was prepared by reactive hot pressing (RHP), at 2000°C for 60 min at 30 MPa under an argon atmosphere, following a 60 min hold at 1700°C without applied pressure before reaching the RHP temperature. TG-DTA results showed that a nitrogen atmosphere inhibited denitrification somewhat and retarded the reaction rate. The chemical composition of the obtained material was consistent with theoretical values. FE-SEM observation showed that in situ-formed SiC and BN phases were of spherical morphology with very fine particle size of ∼100 nm.
    Type of Medium: Electronic Resource
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  • 14
    Electronic Resource
    Electronic Resource
    Westerville, Ohio : American Ceramics Society
    Journal of the American Ceramic Society 84 (2001), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Porous alumina ceramics with unidirectionally aligned continuous pores were fabricated via the slurry coating of fugitive fiber. Cotton thread was coated with ceramic slurry by pulling it through the slurry, and specimens were produced by spooling the coated thread. The obtained porous alumina ceramics had an average pore diameter of 165 μm, 35% open porosity, and a bending strength of 160 MPa. It was suggested that the pore size and the porosity could be adjusted using the diameter of the cotton thread and the solids concentration of the slurry, respectively.
    Type of Medium: Electronic Resource
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  • 15
    Electronic Resource
    Electronic Resource
    Westerville, Ohio : American Ceramics Society
    Journal of the American Ceramic Society 87 (2004), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A dense alumina-silicon carbide (Al2O3–SiC) nanocomposite was synthesized in situ from the reaction of mullite, aluminum, and carbon by reactive hot pressing (RHP). Transmission electron microscopy investigation showed that in situ-formed, nanometer-sized SiC particles were mainly entrapped in the matrix grains, whereas submicrometer-sized particles were located at the grain boundaries or triple points of the Al2O3. In addition, no amorphous phase was observed at the interfaces of the Al2O3 and SiC grains, which indicated strong direct bonding. Fracture-surface analysis by scanning electron microscopy revealed an intrafracture mode. The bending strength of the nanocomposite RHP-treated at 1800°C was 795 ± 160 MPa, and the fracture toughness, measured by the indentation method, was 3.1 MPa·m1/2.
    Type of Medium: Electronic Resource
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  • 16
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Science Inc
    Journal of the American Ceramic Society 88 (2005), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The effect of Y2O3 addition (0–5 wt%) on the densification and properties of reactive hot-pressed alumina (Al2O3)–boron nitride composites based on the reaction between aluminum borate (2Al2O3·B2O3) and aluminum nitride (AlN) was investigated. The densification process was very sensitive to the amount of Y2O3. Compared with a low relative density of 79.3 theoretical density (TD)% for material with no Y2O3 addition, the material density reached 98.6 TD% with 0.25% Y2O3 addition. High Y2O3 additions resulted in the formation of a new phase Al5Y3O12. The grain growth of the Al2O3 matrix was promoted by the Y2O3 addition. Owing to the high density and the small Al2O3 particle size the sample with 0.25% Y2O3 addition demonstrated the highest bending strength of 540 MPa.
    Type of Medium: Electronic Resource
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  • 17
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Science Inc
    Journal of the American Ceramic Society 88 (2005), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Porous Si3N4 ceramics were synthesized by pressureless sintering of green compacts prepared using slip casting of slurries containing Si3N4, 5 wt% Y2O3+2 wt% Al2O3, and 0–60% organic whiskers composed of phenol–formaldehyde resin with solids loading up to 60 wt%. Rheological properties of slurries were optimized to achieve a high degree of dispersion with a high solid-volume fraction. Samples were heated at 800°C in air and sintered at 1850°C in a N2 atmosphere. Porosities ranging from 0% to 45% were obtained by the whisker contents (corresponding to 0–60 vol% whisker). Samples exhibited a uniform pore distribution. Their rod-shaped pore morphology originated from burnout of whiskers, and an extremely dense Si3N4 matrix.
    Type of Medium: Electronic Resource
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  • 18
    Electronic Resource
    Electronic Resource
    Westerville, Ohio : American Ceramics Society
    Journal of the American Ceramic Society 85 (2002), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Previous experimental results showed that a ceramic/superplastic laminate exhibited multiple cracking in ceramic layers during a three-point bending test. In this work, a model analysis has been developed based on bending theory. It reveals that there are two basic processes that occur after a ceramic layer fractures: one is a relaxation process of the residual stress in the ceramic layer, due to the confinement by the superplastic layers; the other is a shear process of superplastic flow, which originates from the difference in strain rate between the fractured and unbroken ceramic layers. The total stress in an as-fractured ceramic layer is the sum of the residual stress and a shear-accumulated stress, depending on time. When the total stress at a critical distance from the fractured surface exceeds the fracture strength of a ceramic layer, new cracking occurs. There is a critical roller speed below which no multiple cracking occurs, depending on specimen dimensions and material properties. The number of multicracks in one ceramic layer decreases with the progress of the fracture in the laminate, due to the decrease in shear-accumulated stress. The theoretical predications are in good agreement with the experimental results. Moreover, the variations in fracture energy of the laminate due to the multiple cracking are discussed in detail.
    Type of Medium: Electronic Resource
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  • 19
    Electronic Resource
    Electronic Resource
    Westerville, Ohio : American Ceramics Society
    Journal of the American Ceramic Society 82 (1999), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A high-temperature multilayer composite (MLC) with hot hard layers and superplastic layers was proposed in this communication. The hard layer can provide the MLC high-temperature strength; the superplastic layer can deform plastically at high temperatures, disperse the applied stress, and stop the crack from advancing. Such an MLC was prepared via tape casting in the Al2O3/MoSi2+Mo2B5 system in the present work; in this system, Al2O3 was the hard layer and MoSi2+Mo2B5 was the superplastic layer. The microstructures and the stress-displacement behaviors of the MLCs were investigated. Finally, the design rules for the high-temperature MLCs were discussed briefly.
    Type of Medium: Electronic Resource
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  • 20
    ISSN: 1476-4687
    Source: Nature Archives 1869 - 2009
    Topics: Biology , Chemistry and Pharmacology , Medicine , Natural Sciences in General , Physics
    Notes: [Auszug] Cell-cycle transitions are driven by waves of ubiquitin-dependent degradation of key cell-cycle regulators. SCF (Skp1/Cullin/F-box protein) complexes and anaphase-promoting complexes (APC) represent two major classes of ubiquitin ligases whose activities are thought to regulate primarily the ...
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