ISSN:
0044-2313
Keywords:
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
Pseudochalcogen Compounds. XVIII. Cyanamidolysis of Organophosphoryl-(phosphonyl-) chloridesCyanamidolytic reactions of organophosphoryl- and -phosphonyl chlorides are leading in dependence on the conditions of the reactions to metal-organo-cyanamidophosphates, M[(RO)2P(Y)NCN], and -cyanamidophosphonates, M[(RO)R'P(Y)NCN], M2[RP(Y)(NCN)2] respectively, as well as to the corresponding organo phosphoryl (phosphonyl) hydrogencyanamides, (RO)2P(Y)NHCN, (RO)R'P(Y)NHCN, RP(Y)(NHCN)2 and to Bis-(organophosphoryl)- and Bis-(organophosphonyl)-carbodiimides, (RO)2P(Y)-NCN-P(Y)(OR)2, (RO)R'P(Y)-NCN-P(Y)R' (OR). (Y: O, S). Conditions for synthesis as well as properties and structures of the new compounds are discussed on the basis of characteristic IR- and 31P-NMR-data.
Notes:
Cyanamidolysereaktionen an Organophosphoryl- und -phosphonyl-chloriden führen in Abhängigkeit von den gewählten Reaktionsbedingungen zu Metall-organo-cyanamidophosphaten, M[(RO)2P(Y)NCN], Metall-organo-cyanamidophosphonaten, M[(RO)R'P(Y)NCN], M2[RP(Y)(NCN)2] (Y: O, S), ferner zu den entsprechenden Organophosphoryl-(phosphonyl)-hydrogencyanamiden, (RO)2P(Y)NHCN, (RO)R'P(Y)NHCN, RP(Y)(NHCN)2 sowie zu Bis-(organophosphoryl)-carbodiimiden, (RO)2P(Y)—NCN—P(Y)(OR)2 und Bis-(organophosphonyl)-carbodiimiden, (RO)R'P(Y)-NCN-P(Y)R'(OR). Synthesebedingungen, Strukturen und Eigenschaften der neuen Verbindungen werden anhand der charakteristischen IR- und 31P-NMR-Daten diskutiert.
Additional Material:
1 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/zaac.19895680106
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