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  • 1
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 40 (1994), S. 1929-1939 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The breakup of droplets in an inhomogeneous flow is the key to emulsification. Frequently, the local flow experienced by the drops is a (quasi-) simple shear flow. The breakup of droplets in a steady, simple shear flow in the absence of emulsifiers has been studied extensively. In the presence of emulsifiers, the droplet interface may acquire viscoelastic properties, which are important in the prevention of coalescence, but their influence on droplet breakup has not been established solidly. This article reports on a phenomenological approach, which links the droplet breakup dynamics to the interfacial viscoelasticity, identifying the latter with the elasticity modulus of a deforming planar interface. Over a viscosity ratio range of three decades, the results have been found to agree with the model, which uses only independently known quantities derived from equilibrium interfacial tension properties.
    Additional Material: 12 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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  • 2
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 43 (1997), S. 1436-1447 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Droplet breakup in laminar flows is important in emulsification processes and polymer blending. The influence of surfactants on droplet deformation and breakup in a plane hyperbolic flow was studied experimentally in an opposed-stream device. As in the case of simple shear flow, the inhomogeneity of the surfactant distribution along the droplet interface has a pronounced effect. Our results are qualitatively consistent with other numerical studies for droplet breakup in an axisymmetric elongational flow. Also a striking similarity is noted with other experimental observations for the deformation and breakup of polymeric drops in a quasi-steady-plane hyperbolic flow. The critical capillary number for droplet breakup in the experiments correlates with the interfacial viscoelasticity, and a reformulation of the numerical framework in terms of interfacial elasticity parameters is suggested for future numerical work including other linear flows.
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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