ISSN:
0044-2313
Keywords:
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
Behaviour of Mono- and Diorganylphosphane Sulphides towards Metal Carbonyl Systems. XX. Preparation, Properties, and Crystal Structure of Ammine(tetracarbonyl)-(dimethylthiophosphinito)rheniumStarting from the P isomer (OC)4BrReP(CH3)2SH, (OC)4NH3ReP(CH3)2S is obtained via the heterocycle [—(OC)4ReP(CH3)2S—]2 by cleaving the Re—S-bond with ammonia. The 1H and 31P{1H} n.m.r. spectra and some i.r. and Raman data were discussed. The compound crystallizes monoclinic in the space group P21/c with Z = 4.
Notes:
(OC)4NH3ReP(CH3)2Serhält man aus dem P-Isomeren (OC)4BrReP(CH3)2SH über den Heterocyclus [—(OC)4ReP(CH3)2S—]2 durch Spaltung der Re=S-Bindung mit Ammoniak. Die 1H- und 31P-{1H}-NMR-Spektren sowie einige IR- und Raman-Daten werden diskutiert. Die Verbindung kristallisiert monoklin in der Raumgruppe P21/c mit Z = 4.
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/zaac.19794560117
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