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  • 1
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 42 (1991), S. 779-790 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Five series of blends were obtained by mixing five polyurethanes (PUR), based on poly-propyleneoxide, MDI, and butanediol, with polypropylene (PP). The structure of PUR was varied by varying soft segment length (MW = 1000 and 2000) and soft segment concentration (50, 60, and 70%). It has been shown that interaction between PUR and PP was better in the case of PUR with the polyol of MW = 1000. The addition of lower molecular weight PUR produced an easy flowing material in the molten state, comparable with the “control rheology PP.” The morphology of the blends changed with PUR concentration. At 30% PUR the dispersed phase tended to agglomerate in the form of long cylinders. Mechanical properties generally were affected by the change of morphology.
    Additional Material: 12 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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  • 2
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 49 (1993), S. 1659-1669 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Interaction between polypropylene matrix and carbon black was examined by measuring physical, mechanical, and electrical properties. It has been shown that presence of carbon black influences the morphology and crystallinity of the matrix. Strong interaction was observed directly by electron microscopy and indirectly by the rise of the modulus of elasticity. The effect of carbon black on strength and physical properties of the composites is discussed. © 1993 John Wiley & Sons, Inc.
    Additional Material: 12 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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  • 3
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 59 (1996), S. 301-310 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Toughening of polypropylene was carried out by adding two types of ethylene-propylene rubber (EPR) having different ethylene content, and three commercial types of EPR containing high density polyethylene (PE). The concentration of EPR was varied from 0-30%. Globular morphology of the dispersed phase was observed at all concentrations. Average particle size of the dispersed phase (EPR) was about 2-4 μm with about 10% within the 0.5-1 μm range. Although most of the properties were not affected by the presence of polyethylene, high notched Izod impact strength was achieved only with samples containing PE. Melt flow rate, yield strength and modulus were found to decrease almost linearly with increasing elastomer concentration in the blend. Elongation at break was enhanced by the addition of EPR, particularly those containing PE. The contribution of PE to the properties was explained by the specific EPR/PE particle morphology (core-shell or interpenetrating) but the exact mechanism of toughening of PP with EPR in the presence of PE is not clear. © 1996 John Wiley & Sons, Inc.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
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