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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Journal of materials science 20 (1985), S. 3705-3715 
    ISSN: 1573-4803
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract Fracture measurements have been made using a high pressure technique on three batches of uPVC corresponding to distinct levels of gelation.K c values correlate with methylene chloride attack in the established manner, but are low in comparison with room pressure values measured at comparable strain rates. This is linked with the presence of stress whitening on the fracture surface at room pressure, its absence at high pressure, and its diminution at room pressure when testing speed is increased, when lowK c values are also recorded. The results are successfully interpreted in terms of a multiple craze slow crack growth model, in which cracking in the tests at room pressure and slow speed is assumed to start at theK c measured at high pressure, and slow crack growth follows as the load on the specimen continues to increase until the specimen fails catastrophically. A reasonable choice of parameters then gives a good prediction of the observed collapse loads.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Journal of materials science 5 (1986), S. 1109-1110 
    ISSN: 1573-4811
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Journal of materials science 21 (1986), S. 2049-2058 
    ISSN: 1573-4803
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract The impact behaviour of polyethersulphone has been studied using a specially constructed instrumented impact testing machine. This machine is of the pendulum type and the samples are fractured in three-point bend loading. It is shown that accurate force/deformation curves can be obtained, in spite of complications due to flexural vibrations of the test sample. Measurements were made on both sharp-notched and blunt-notched specimens over a range of crack lengths. It was found that the sharp-notched samples could be analysed in terms of fracture toughness, G C, whereas the blunt-notched samples corresponded to a constant critical stress at the root of the notch. The importance of multiple crazes at the crack tip in bluntnotched specimens is emphasized. It is also shown that ageing reduces the fracture toughness, while on the other hand, the critical stress observed in blunt-notched specimens, which has been associated with the craze initiation stress, is not affected by ageing.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Springer
    Journal of materials science 30 (1995), S. 5328-5334 
    ISSN: 1573-4803
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract The compressive yield behaviour of poly(2,2′-m-phenylene-5,5′-bibenzimidazole) (PBI) has been studied over a wide range of temperatures. The tensile behaviour was also studied under superimposed hydrostatic pressure. In both cases wet and dry samples were examined and the results revealed the considerable effects of moisture on the mechanical properties of PBI. The results of all these tests show that PBI has a remarkably high shear yield stress at room temperature. This results in a very high compressive yield stress and a very high tensile yield stress observed under superimposed hydrostatic pressure when brittle failure from surface flaws is prevented. It is concluded on the basis of quantitative analysis that the yield mechanism in PBI at room temperature is initiation controlled, as in a metal or ceramic, rather than a velocity controlled, thermally activated, viscoelastic process which is generally considered applicable in polymers.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Springer
    Journal of materials science 27 (1992), S. 2799-2806 
    ISSN: 1573-4803
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract The fracture behaviour of a range of polyethylenes with different molecular weights and side group content has been studied by means of a novel high-pressure tensile testing facility. The normally ductile specimens became brittle at high pressures, e.g. 700 MPa, so that the test results could be studied by means of linear elastic fracture mechanics. Oriented specimens were prepared by die-drawing to draw ratios of 5∶1 and 9.5∶1. The performance of the isotropic and oriented (longitudinal and transverse directions) materials were assessed using their K IC values. Results were carefully compared in order to study the effects of molecular weight and low concentrations of small side groups on the fracture behaviour of polyethylene. The structure of the oriented polymers was characterised using wide-angle X-ray diffraction.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Springer
    Journal of materials science 22 (1987), S. 1437-1442 
    ISSN: 1573-4803
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract Yield-stress measurements on amorphous polyethylene terephthalate film are presented covering five decades of strain rate at temperatures from just below the glass transition (≈ 60° C) to −160° C. The data were obtained by combining measurements from a conventional Instron machine with data from a high-speed tensile tester capable of applying strain rates of up to 50 sec−1. Five different failure modes have been identified over this extensive range of test conditions. All data from tests which show a clear yield point can be described accurately by an extension of the Ree Eyring approach to include two processes. The process which is only important at low temperatures correlates well with theβ-process observed in dynamic mechanical experiments.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Springer
    Journal of materials science 27 (1992), S. 3969-3976 
    ISSN: 1573-4803
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract The fracture initiation behaviour of injection-moulded plaques of a liquid-crystal polymer is described. Attention is restricted to cracks in the plane of the plaques propagating along the mould fill direction. The material is both anisotropic and inhomogeneous; the latter factor is accommodated by adopting a skin-core model of the plaque structure. The inhomogeneity leads to mixed mode (Modes I and II) fracture in some cases, and both single and mixedmode testing is used. The results can be represented in terms of either stress intensity or strain energy release rate by simple mixed-mode failure criteria.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Springer
    Journal of materials science 19 (1984), S. 3796-3805 
    ISSN: 1573-4803
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract Fracture studies of polyethersulphone have been undertaken using the double torsion geometry, in particular to establish the effects of ageing and crack speed on fracture toughness. The stability of crack growth was found in all cases to be very dependent on initial notching. If by suitable techniques, e.g. fatigue, a craze was formed at the notch root the subsequent crack growth was found to be stable, with a craze ahead of the growing crack. Under these conditions only a slight dependence of fracture toughness on crack speed was observed, with no significant differences between material aged for 5 years at room temperature and freshly moulded samples. The dimensions of the observed craze were found to be very similar to those of crazes observed in a parallel study using compact tension geometry and lead to comparable values for craze stress and crack opening displacement. In many instances unstable crack growth was observed, often described as “stick-slip”. This was often associated with the absence of a craze at the crack tip, perhaps due to a damage zone created during razor notching. The initiation load and load for crack arrest were determined and used to calculate initiation and arrest values for the fracture toughness as a function of the applied deformation rate. It was found that these values converged at high crosshead speeds to a value independent of ageing, although for the freshly moulded material the initiation values were significantly higher, and the arrest values lower. Electrically conducting grids were used to establish that crack speeds up to 400 m sec−1 occur during stick-slip crack growth. A detailed discussion is presented of conditions required for stable and unstable crack growth in polyethersulphone.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Springer
    Journal of materials science 19 (1984), S. 413-422 
    ISSN: 1573-4803
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract The failure of two grades of polyethylene has been studied using the technique of torsion under superposed hydrostatic pressure. The behaviour of unnotched samples of both grades was ductile at all pressures and strain-rates. However, at sufficiently high pressures both grades of polyethylene (including a tough copolymer) failed in a brittle manner when a surface notch was exposed to a suitable pressure fluid. Measurement of fracture stresses for various notch depths lead to a value for a critical stress intensity factor at each of several pressures. A linear extrapolation was then used to estimate the critical stress intensity factor at atmospheric pressure to be 1.11±0.05 MN m−3/2 and 1.68±0.08 MN m−3/2 for the homopolymer and copolymer, respectively. An independent measurement at atmospheric pressure for the homopolymer using compact tension geometry yielded a value of 1.28±0.02 MN m−3/2 confirming the accuracy of the extrapolation procedure and that the effect of the environment on the behaviour was not substantial.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    Springer
    Journal of materials science 15 (1980), S. 2471-2477 
    ISSN: 1573-4803
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract A simple model is proposed to explain transitions from crazing or fracture to shear yielding and vice-versa with increasing superposed pressure. The model is based on an estimate of the local tensile component of stress in the vicinity of a flaw, distinguishing between the different physical situations which arise depending on whether or not the pressurizing medium penetrates the flaw. The model explains naturally many observations of specimens failing in a brittle manner in nominally compressive stress fields.
    Type of Medium: Electronic Resource
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