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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Journal of materials science 32 (1997), S. 4821-4832 
    ISSN: 1573-4803
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract The compaction of gel-spun high molecular weight polyethylene (PE) fibre, SPECTRA 1000, has been investigated for a range of compaction temperatures between 142°–155°C. Differential scanning calorimetry (DSC), scanning electron microscopy (SEM) and broad-line nuclear magnetic resonance (NMR) techniques have been used to examine the structure of the compacted materials and to determine the compaction mechanisms. With increasing compaction temperature, the flexural properties of the compacted materials did not show any significant change up to 154°C, but large changes were observed if the temperature was increased from 154 to 155°C. DSC and SEM studies revealed that no evident surface melting and recrystallization occurred during hot compaction in the temperature range 144–154°C, although the rigid crystalline fraction measured by NMR for all compacted materials is significantly lower than that for the original fibre. Significant transverse strength is also developed at the lower compaction temperatures, and this also only markedly increases on going from 154 to 155°C. Structural investigations show how the fibres deform so as to interlock, and localized welding occurs, so as to bond each fibre to its neighbour. This is distinct from the melting and recrystallization at the surface of the fibres previously observed in melt spun fibres.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Journal of materials science 31 (1996), S. 371-379 
    ISSN: 1573-4803
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract The measurement of the elastic constants of several highly oriented thermoplastic polymer fibres is described. The method makes use of the hot-compaction process, developed and patented in this laboratory, which enables a solid section of highly oriented polymer to be produced from an aggregate of highly oriented fibres. As only a small fraction of the original fibre is melted and recrystallized during the process, the compacted materials offer a unique opportunity for measuring fibre properties in the bulk. An ultrasonic immersion technique is used to measure the elastic properties of the compacted materials, from which the properties of the polymer fibres are inferred. The experimentally determined fibre elastic properties have been compared with other oriented polymer materials to assess any similarities in elastic anisotropy between different methods for producing fibre orientation, and compared with theoretical upper limits for the fibre elastic properties based on theoretical estimates for the polymer crystal unit cell appropriately averaged for hexagonal symmetry using the aggregate model.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Journal of materials science 31 (1996), S. 1157-1163 
    ISSN: 1573-4803
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract Investigation of the compaction of unidirectionally arranged high-tenacity polypropylene fibres is described. A combination of techniques, with the major emphasis being morphological studies, show that controllable “selective” surface melting is not achieved at a high enough proportion to give substantial fibre-to-fibre bonding, and hence good lateral strengths.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Springer
    Journal of materials science 21 (1986), S. 2049-2058 
    ISSN: 1573-4803
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract The impact behaviour of polyethersulphone has been studied using a specially constructed instrumented impact testing machine. This machine is of the pendulum type and the samples are fractured in three-point bend loading. It is shown that accurate force/deformation curves can be obtained, in spite of complications due to flexural vibrations of the test sample. Measurements were made on both sharp-notched and blunt-notched specimens over a range of crack lengths. It was found that the sharp-notched samples could be analysed in terms of fracture toughness, G C, whereas the blunt-notched samples corresponded to a constant critical stress at the root of the notch. The importance of multiple crazes at the crack tip in bluntnotched specimens is emphasized. It is also shown that ageing reduces the fracture toughness, while on the other hand, the critical stress observed in blunt-notched specimens, which has been associated with the craze initiation stress, is not affected by ageing.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Springer
    Journal of materials science 30 (1995), S. 5879-5884 
    ISSN: 1573-4803
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract An analytical method is presented which enables the elastic constants of the fibres in a unidirectional composite to be estimated from a knowledge of the elastic constants of the composite and the matrix resin. Results are presented for polyethylene fibre/epoxy resin and carbon fibre/epoxy resin composites, and it is shown that the predicted fibre constants are, in both cases, close to those obtained from other methods.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Springer
    Journal of materials science 30 (1995), S. 615-622 
    ISSN: 1573-4803
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract A process is described for the successful compaction of polyethylene terephthalate fibres. The measurement of mechanical properties shows that a very high proportion of the original fibre properties are retained and that the compacted samples have a good degree of coherence. Electron microscopy studies of suitably etched samples reveals the effect of the compaction temperature on the structure of the compacted samples.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Springer
    Journal of materials science 30 (1995), S. 601-606 
    ISSN: 1573-4803
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract The compaction of high-modulus melt-spun polyethylene fibres has been investigated for compaction temperatures above the optimum. After such treatment the specimens are liable to be non-uniform because of differential melting. Individual compacted fibres are observed to melt not only from the outside inwards, but also in certain internal regions, depending upon the availability of local free volume. The regions of different stability have been identified and inferences drawn concerning the structure of the initial fibres. It is suggested in particular that the longitudinal regions of deficit density (which exhibit cratering in transverse sections and melt before their surroundings) are a result of initial crystallization occurring within a rigid framework inside the fibre, possibly nucleated on a strained molecular network. The presence of banded recrystallization around residual fibres demonstrates that this phenomenon develops via interaction of neighbouring lamellae as they grow.
    Type of Medium: Electronic Resource
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  • 8
    ISSN: 1573-4803
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract In the process of hot compaction developed at the University of Leeds, high-modulus fibres are compacted to form coherent thick-section products with stiffnesses unobtainable by current processing techniques. Using high-modulus polyethylene fibres (trade name TENFOR) produced by the melt-spinning/hot-drawing route as the starting material, it was discovered that under optimum conditions of pressure and temperature it is possible controllably to melt a small proportion of each fibre. On cooling, this molten material recrystallizes to bind the structure together and fill all the interstitial voids in the sample, leading to a substantial retention of the original fibre properties. For a hexagonal close-packed array of cylinders, only 10% of melted material is needed for this purpose. If the compaction temperature is too low, there is insufficient melt to fill the interstices, the fibres deform into polygonal shapes, and insufficient transverse strength is developed. Above the optimum temperature, the proportion of melt increases, causing the stiffness of the composite to be reduced. The recrystallization of the melt is nucleated on the oriented fibres, giving similarly oriented cylindrulitic growth. Where the regions of melt are large enough, and cooling sufficiently rapid, development away from the nucleus is accompanied by a cooperative rotation in chain orientation, analogous to banding in spherulites.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Springer
    Journal of materials science 28 (1993), S. 316-324 
    ISSN: 1573-4803
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract The production of solid section highly oriented polyethylene by compaction of melt-spun polyethylene fibres is described. Differential scanning calorimetry, X-ray diffraction and electron microscopy have been used to determine the structure of the compacted polymer. The essential feature of the process is shown to be selective surface melting of the fibres to form a polyethylene/polyethylene composite of very high integrity, yet maintaining a very high proportion of the strength and stiffness of the fibres.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    Springer
    Journal of materials science 28 (1993), S. 1107-1112 
    ISSN: 1573-4803
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract The microstructure of aggregates of parallel high-modulus polyethylene fibres, compacted at 138°C to give a composite with good mechanical properties, has been examined. Detail of transverse and longitudinal cross-sections has been revealed by permanganic etching and studied electron microscopically. The fibres pack together irregularly with coordination numbers typically between 4 and 7 and fibre diameters in the range 10–20 μm. Misalignment of fibres is generally close to zero but does occur incrementally, by 10° and more, between successive rows of fibres. A substantial proportion of fibres has deformed, often by shear, during treatment producing a broadening of interfibrillar contacts. A lamellar component of texture is present both between and within fibres. It is inferred to form by melting of those parts of the fibres where there is least constraint on the melt, followed by recrystallization on the fibres as nuclei. The lamellae therefore share the axial orientation of the fibres, while the crystallographic fibre/lamellar contact promotes good transverse properties.
    Type of Medium: Electronic Resource
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