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  • 1
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Industrial & engineering chemistry research 34 (1995), S. 3405-3410 
    ISSN: 1520-5045
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Industrial & engineering chemistry research 27 (1988), S. 707-712 
    ISSN: 1520-5045
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Journal of thermal analysis and calorimetry 37 (1991), S. 319-331 
    ISSN: 1572-8943
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Zusammenfassung Durch Pyrolyse eines Aerosols von Nickelnitratlösung werden feinkörnige, hole, kugelförmige Partikel mit einer durchschnittlichen Größe von einem Mikrometer gebildet. Das durch schnelles Erhitzen auf 450°C erhaltene Aerosolprodukt bestand aus winzigen NiO-Kristallen, aus hydratiertem Nitrat und aus anderen nichtkristallinen Phasen. Durch Erhitzen über 480°C erhält man ausschließlich kristallines NiO. Zum Verständnis der während des Aerosolierungsvorganges ablaufenden Reaktionen wurde in ruhender und dynamischer Luftatmosphäre sowie bei verschiedenen Aufheizgeschwindigkeiten eine Thermoanalyse von Nickelnitrat-Hexahydrat durchgeführt. Im Ergebnis konnte ein Mechanismus für die Zersetzung von Nickel(II)-nitrat-Hexahydrat entwickelt werden.
    Notes: Abstract Fine, hollow, spherical particles with an average size of one micronmeter were formed through pyrolysis of aerosol of nickel nitrate solution. The aerosol product obtained by fast heating to 450°C consisted of tiny crystallites of NiO, hydrated nitrate, and other non-crystalline phase(s). By heating above 480°C, it consisted only of crystalline NiO. To understand the reactions occurring during the aerosolization process, thermal analysis was conducted on nickel nitrate hexahydrate in stagnant and flowing air using different heating rates. The mechanism for the decomposition of nickel(II) nitrate hexahydrate is proposed.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Springer
    Plant and soil 121 (1990), S. 21-30 
    ISSN: 1573-5036
    Keywords: actual N loss ; flooded soils ; 15N balance ; potential N loss ; urea ; water-soluble N
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract One day after application, urea-N remaining in the floodwater and determined as water-soluble N (urea-N + NH4 +-N) was used to calculate the potential N loss from lowland rice soils. Actual N loss calculated from 15N balance measurements using forced air exchange (airflow rate: 20 L min-1) in greenhouse pots. Conditions for variable potential N loss were created by manipulating the method of urea application and duration of presubmergence or by selecting soils with diverse cation exchange capacities (CEC). Potential N loss tended to be lower than actual N loss; the differences were, however, nonsignificant. The method of urea application that led to the lowest potential N loss from a Guthrie silty clay loam (Typic Fragiaquult) also led to the least 15N loss and vice-versa (r=0.99**). Duration of presubmergence did not alter the relationship between potential and actual N loss although it influenced the rate of urea hydrolysis in floodwater. The primary depencence of actual N loss on water-soluble N was maintained in soils differing in CEC (r=0.83**). The association between potential and actual N loss was closer for high-CEC soils (≥ 20 cmol [+] kg-1 soil, r=0.91**) than for low-CEC soils (〈20 cmol [+] kg-1 soil, r=0.85**). Ammonia volatilization could be more closely predicted by potential N loss than could apparent denitrification. The results of this study suggest that potential N loss calculated from one-time determination of water-soluble N in floodwater can be a good index of actual N loss from flooded, puddled rice soils. Notable exceptions are to be expected for soils in which water-soluble N gets lost from floodwater either before (soils with fast urea hydrolysis in floodwater) or after (soils with steady leaching) determination of potential N loss.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Springer
    Plant and soil 122 (1990), S. 21-30 
    ISSN: 1573-5036
    Keywords: actual N loss ; flooded soils ; 15N balance ; potential N loss ; urea ; water-soluble N
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract One day after application, urea-N remaining in the floodwater and determined as water-soluble N (urea-N + NH4 +-N) was used to calculate the potential N loss from lowland rice soils. Actual N loss calculated from15N balance measurements using forced air exchange (airflow rate: 20 L min-1) in greenhouse pots. Conditions for variable potential N loss were created by manipulating the method of urea application and duration of presubmergence or by selecting soils with diverse cation exchange capacities (CEC). Potential N loss tended to be lower than actual N loss; the differences were, however, nonsignificant. The method of urea application that led to the lowest potential N loss from a Guthrie silty clay loam (Typic Fragiaquult) also led to the least15N loss andvice-versa (r=0.99**). Duration of presubmergence did not alter the relationship between potential and actual N loss although it influenced the rate of urea hydrolysis in floodwater. The primary depencence of actual N loss on water-soluble N was maintained in soils differing in CEC (r=0.83**). The association between potential and actual N loss was closer for high-CEC soils (≥ 20 cmol [+] kg-1 soil, r=0.91**) than for low-CEC soils (〈20 cmol [+] kg-1 soil, r=0.85**). Ammonia volatilization could be more closely predicted by potential N loss than could apparent denitrification. The results of this study suggest that potential N loss calculated from one-time determination of water-soluble N in floodwater can be a good index of actual N loss from flooded, puddled rice soils. Notable exceptions are to be expected for soils in which water-soluble N gets lost from floodwater either before (soils with fast urea hydrolysis in floodwater) or after (soils with steady leaching) determination of potential N loss.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Springer
    Plant and soil 121 (1990), S. 31-39 
    ISSN: 1573-5036
    Keywords: dry soil application ; lowland rice ; 15N-labeled urea ; N-use efficiency ; wet soil application
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract A transplanted crop of IR36 rice (Oryza sativa L.) was grown in greenhouse pots on three different soils [cation exchange capacity (CEC) 5 to 62 cmol (Na+) kg-1 soil] in two different experiments. Efficiency of 15N-labeled urea incorporated into presubmerged wet soils was compared with that of 15N-urea broadcast on dry soils (air-dry soil, moisture content 40 to 50 g kg-1 soil) followed by submergence and puddling. With wet soil application, 15N loss varied between 35% and 50%, whereas it was less than 20% with dry soil application. Nitrogen-15 loss increased with an increase in the rate of N applied and a fall in soil CEC, especially with wet soil application. Variations in 15N loss followed the buildup of water-soluble N (urea-N + NH4 +-N) in floodwater, i.e., the potential N loss. Lack of correlation between 15N loss and potential N loss with dry soil application was attributed to increased susceptibility to nitrification-denitrification of urea deep-placed by infiltrating water. Data on N loss were consistent with the findings on N use efficiency. Whether measured by grain yield response, N uptake, apparent recovery, or 15N recovery, a striking improvement in N use efficiency occurred when urea was applied to dry soil prior to submergence instead of to puddled wet soils. As the duration of submergence between urea application to dry soil and transplanting was increased from 0 to 7 days, improvement in 15N recovery by plant and accompanying grain yield response decreased. On an overall basis, this greenhouse research has demonstrated the principle that total N loss from rice fields is predominantly controlled by the proportion of applied urea entering the floodwater. The research also provides basic information on improving current N management practices in irrigated lowland rice culture.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Springer
    Plant and soil 122 (1990), S. 31-39 
    ISSN: 1573-5036
    Keywords: dry soil application ; lowland rice ; 15N-labeled urea ; N-use efficiency ; wet soil application
    Source: Springer Online Journal Archives 1860-2000
    Topics: Agriculture, Forestry, Horticulture, Fishery, Domestic Science, Nutrition
    Notes: Abstract A transplanted crop of IR36 rice (Oryza sativa L.) was grown in greenhouse pots on three different soils [cation exchange capacity (CEC) 5 to 62 cmol (Na+) kg-1 soil] in two different experiments. Efficiency of15N-labeled urea incorporated into presubmerged wet soils was compared with that of15N-urea broadcast on dry soils (air-dry soil, moisture content 40 to 50 g kg-1 soil) followed by submergence and puddling. With wet soil application,15N loss varied between 35% and 50%, whereas it was less than 20% with dry soil application. Nitrogen-15 loss increased with an increase in the rate of N applied and a fall in soil CEC, especially with wet soil application. Variations in15N loss followed the buildup of water-soluble N (urea-N + NH4 +-N) in floodwater,i.e., the potential N loss. Lack of correlation between15N loss and potential N loss with dry soil application was attributed to increased susceptibility to nitrification-denitrification of urea deep-placed by infiltrating water. Data on N loss were consistent with the findings on N use efficiency. Whether measured by grain yield response, N uptake, apparent recovery, or15N recovery, a striking improvement in N use efficiency occurred when urea was applied to dry soil prior to submergence instead of to puddled wet soils. As the duration of submergence between urea application to dry soil and transplanting was increased from 0 to 7 days, improvement in15N recovery by plant and accompanying grain yield response decreased. On an overall basis, this greenhouse research has demonstrated the principle that total N loss from rice fields is predominantly controlled by the proportion of applied urea entering the floodwater. The research also provides basic information on improving current N management practices in irrigated lowland rice culture.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 30 (1984), S. 50-55 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Intermediate phases and reactions occurring on decomposing diammonium hydrogen phosphate, ammonium para molybdate, sodium tungstate dihydrate and ammonium meta vanadate were established by thermal analysis and X-ray examination.These salts promote fabric degradation at low temperatures but are effective at high temperatures. Diammonium hydrogen phosphate produced maximum amount of gases, absorbed the highest amount of heat and gave the highest fire retardation above 350°C.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    International Journal of Chemical Kinetics 19 (1987), S. 105-113 
    ISSN: 0538-8066
    Keywords: Chemistry ; Physical Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Solid solutions of Cu2O alone and Cu2O with ZnO or Cr2O3 in ZnO · Cr2O3 as well as solid solutions of ZnO in Cu2O · Cr2O3 have activities and selectivities for methanol synthesis comparable to solid solutions of Cu2O in ZnO. Addition of a secondary phase to these solid solutions limits the grain growth and produces higher surface areas.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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