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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Cellular and molecular life sciences 40 (1984), S. 29-36 
    ISSN: 1420-9071
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Medicine
    Notes: Summary Cadmium is present naturally in the air mainly as a result of volcanic emissions and release by vegetation. Anthropogenic sources, which overall give rise to emissions one order of magnitude greater than natural sources, are largely primary non-ferrous metals production and waste incineration. Measured concentrations of airborne cadmium are typically 〈 1 ng m−3 at remote sites, 0.1–10 ng m−3 at rural sites and 1–100 ng m−3 at urban and industrial sites, dependent upon the nature and proximity of local sources. Particle sizes are generally 〈2 μm, and often considerably smaller, consistent with an anthropogenic source and a long atmospheric life-time. Cadmium deposition to the land occurs with fluxes varying from 0.05 ng cm−2 month−1 in Greenland to circa 1000 ng cm−2 month−1 in the vicinity of major industrial sources. The possible significance of a motor vehicular source of airborne cadmium is also reviewed.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Water and environment journal 9 (1995), S. 0 
    ISSN: 1747-6593
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: This paper presents data on the distribution of seven pesticides in an agricultural catchment which is located within the Agricultural Development and Advisory Service farm at Rosemaund, 11 km north-east of Hereford, UK. Data for aldicarb, atrazine, carbofuran, dimethoate, MCPA and isoproturon, are available for both the soil and surface waters (drain and stream water), with simazine data available only for the stream. Measurements were taken before and after pesticide application, which was made following normal agricultural practice. Soil residue data showed the degradation rates of the pesticides to be within the range of literature values. Pesticide levels in the stream and drains during runoff events following rainfall ranged from below detection limits (typically 0.02-0.1 μg/1), to 264 μg/1 (for carbofuran). Over 90% of the events had detectable maximum concentrations. The percentage of pesticide applied, which was removed during individual rainfall events, was calculated. The maximum value estimated was 1.1%, again for carbofuran. Most of the events gave values several orders of magnitude below this value.The data have been used to try to validate a range of models which could be used for screening new pesticides or for informing decisions on the use of existing pesticides. The results of the validations are summarized.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Oxford, UK : Blackwell Publishing Ltd
    Water and environment journal 11 (1997), S. 0 
    ISSN: 1747-6593
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Data are presented on four pesticides applied to agricultural land at the Agricultural Development Advisory Service, Rosemaund, in the west of England. The farm covers a well-defined and isolated water basin of cracking heavy clay loam soils drained by a single stream. Levels of the relatively particle-bound pesticides trifluralin, deltamethrin, chlorpyrifos and fenpropimorph were measured in drainage water and field soils following application. Observed concentrations in water were generally below 1 μg/l with occasional peak levels exceeding 10 μg/l during storm rainfall events. Unexpectedly high peak levels of deltamethrin of around 2 μg/l highlighted significant bypass flow mechanisms from the surface soils during the autumn. Additional bioassay experiments showed that levels of chlorpyrifos, lethal to Gammarus pulex, reached the stream during spring 1993. The Rosemaund farm has been the site of a continuing investigation into the movement of agricultural pesticides to surface waters since 1987, and this report represents the final work conducted in the autumn of 1992 and spring 1993.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Oxford [u.a.] : International Union of Crystallography (IUCr)
    Acta crystallographica 51 (1995), S. 2683-2685 
    ISSN: 1600-5759
    Source: Crystallography Journals Online : IUCR Backfile Archive 1948-2001
    Topics: Chemistry and Pharmacology , Geosciences , Physics
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Oxford [u.a.] : International Union of Crystallography (IUCr)
    Acta crystallographica 48 (1992), S. 717-720 
    ISSN: 1600-5759
    Source: Crystallography Journals Online : IUCR Backfile Archive 1948-2001
    Topics: Chemistry and Pharmacology , Geosciences , Physics
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Oxford [u.a.] : International Union of Crystallography (IUCr)
    Acta crystallographica 49 (1993), S. 1852-1854 
    ISSN: 1600-5759
    Source: Crystallography Journals Online : IUCR Backfile Archive 1948-2001
    Topics: Chemistry and Pharmacology , Geosciences , Physics
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Oxford [u.a.] : International Union of Crystallography (IUCr)
    Acta crystallographica 47 (1991), S. 2241-2242 
    ISSN: 1600-5759
    Source: Crystallography Journals Online : IUCR Backfile Archive 1948-2001
    Topics: Chemistry and Pharmacology , Geosciences , Physics
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Oxford [u.a.] : International Union of Crystallography (IUCr)
    Acta crystallographica 49 (1993), S. 1072-1075 
    ISSN: 1600-5759
    Source: Crystallography Journals Online : IUCR Backfile Archive 1948-2001
    Topics: Chemistry and Pharmacology , Geosciences , Physics
    Type of Medium: Electronic Resource
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  • 9
    ISSN: 1573-0662
    Keywords: Heterogeneous reaction ; N2O5 ; annular reactor ; reaction probability
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Geosciences
    Notes: Abstract A method for the estimation of the reaction probability of the heterogeneous N2O5+H2O → 2HNO3 reaction using the deposition profile in a laminar flow tube, in which the walls are coated with the condensed aqueous phase of interest, is presented. The production of gas phase nitric acid on the surface followed by its absorption complicates the deposition profiles and hence the calculation of the reaction probability. An estimation of the branching ratio for this process enables a more appropriate calculation to be carried out. Reaction probabilities of N2O5 on substances including some normally constituting atmospheric aerosols, NaCl, NH4HSO4, as well as Na2CO3 are estimated and found to depend on relative humidity and characteristics of the coating used. These fell within the range (0.04–2.0)×10−2.
    Type of Medium: Electronic Resource
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  • 10
    ISSN: 1573-0662
    Keywords: hydroxyl radical ; troposphere ; modelling ; steady state
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Geosciences
    Notes: Abstract Calculated and observed hydroxyl (OH) fields are presented. Calculated OH was obtained in three ways using (1) a photochemical box-model (2) a simple OH steady state approach and (3) a variant on (2) – the ‘multiple equation steady state’ approach which assumes steady state for OH, HO2 and RO2 and hence obtains three simultaneous, non linear, equations. All three methods used data collected in June 1995 during the Weybourne Atmospheric Observatory Summer Experiment (WAOSE'95). Julian Days 169, 178, 179 and 180 displayed especially good data capture and were consequently chosen for study. The two steady state methods are essentially driven purely by observations and derive OH from the ratio of the relevant source and sink terms. The box-model was constrained where possible to observations; remaining unmeasured volatile organic compounds (VOCs) were initialised to an arbitrary low value of 10 ppt. Agreement between theory and experiment was usually around 50% and often better than this value, especially on J169, though discrepancies of up to a factor of 3 were occasionally apparent. Despite the inherent scatter, neither the box-model nor the simple steady state method were found to consistently over-estimate OH (a common feature of many numerical approaches) although this did occur to a certain extent using the multiple equation steady state approach, probably due to breakdowns in the steady state approximation. More data spread was evident in the box-model approach compared with the other methods. An analysis of the major sources and sinks of OH is presented for the three methods of calculation. Calculated and observed peroxy radicals are also presented. Calculated peroxy radicals were generally lower than that observed at night yet higher, sometimes by up to a factor of 7, during the day. Possible explanations for this result are explored.
    Type of Medium: Electronic Resource
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