ISSN:
1662-0356
Source:
Scientific.Net: Materials Science & Technology / Trans Tech Publications Archiv 1984-2008
Topics:
Natural Sciences in General
,
Technology
Notes:
Solvothermal reaction of aluminum alkoxides in various alcohols at 250-300 oC yieldedalkyl derivatives of boehmite (alkoxyalumoxanes; AlO(OH)1-x(OR)x) in which alkyl groups wereincorporated between the boehmite layers through the covalent bondings. In the present work, poretextures of aluminas prepared by calcination of the products were examined. The alumina obtainedfrom the ethyl derivative of boehmite had a broad pore-size distribution, while the pore-size of thealumina obtained from the dodecyl derivative of boehmite distributed in a narrow range in themesopore region. The mode pore diameter of the latter alumina increased with the increase incalcination temperature (600 oC, 39 Å; 800 oC, 54 Å; 1000 oC, 74 Å), but narrow pore-sizedistribution was maintained even after calcination at high temperatures
Type of Medium:
Electronic Resource
URL:
http://www.tib-hannover.de/fulltexts/2011/0528/01/42/transtech_doi~10.4028%252Fwww.scientific.net%252FAST.45.2153.pdf
Permalink