ISSN:
1572-901X
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Summary Bis(cyclopentadienyl)titanium(IV) diisothiocyanate [(Cp)2-Ti(NCS)2] reacts with MCl2 (M = Cu, Pd or Pt), [CuCl(PPh3)3], [RuCl2(PPh3)3] and [RuCl2(DMSO)4] (DMSO = dimethylsulphoxide) giving solid compounds of stochiometry [(Cp)2Ti(μ-NCS)2MCl2] (M = Cu, Pd or Pt), [(Cp)2Ti(μ-NCS)2CuCl(PPh3)], [(Cp)2Ti(μ-NCS)2-RuCl(PPh3)2]Cl and [(Cp)2Ti(μ-NCS)2RuCl2(DMSO)2]. These products have been characterized by physicochemical and spectroscopic methods.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00141519
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