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  • 1
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part B: Polymer Physics 36 (1998), S. 2683-2689 
    ISSN: 0887-6266
    Keywords: interfacial tension ; square gradient theory ; equation-of-state theory ; polystyrene/poly(methyl methacrylate) blend ; polystyrene/poly(dimethyl siloxane) blend ; Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Interfacial tension between immiscible polymer pairs was predicted by using a square gradient theory in conjunction with the Flory-Orwoll-Vrij equation-of-state expression for the free energy of mixing. The contact interaction parameter was determined by fitting the equation-of-state theory to experimental cloud points taken from the literature, and the square gradient coefficient was estimated from the relation derived from a scattering function. The modified square gradient theory could successfully predict both the magnitude and temperature dependence of interfacial tension between polystyrene and poly(methyl methacrylate), although no adjustable parameters were used in calculating interfacial tension. The molecular weight dependence of interfacial tension was also successfully predicted. The contribution of free volume on interfacial tension is analyzed for two systems: polystyrene/poly(methyl methacrylate) and polystyrene/poly(dimethyl siloxane) blends. © 1998 John Wiley & Sons, Inc. J Polym Sci B: Polym Phys 36: 2683-2689, 1998
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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  • 2
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 30 (1990), S. 1513-1522 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: An Iterative Boundary Pressure Reflection (IBPR) method has been developed to improve the accuracy of the flow front generation and transient mold filling simulation in injection molding. The method iteratively calculates the virtual pressure reflection, either positive or negative, at the impinging melt front nodes which are to be relocated subsequently according to the new pressure field. The scheme is formulated into a finite element program using a power-law model and applied to the filling of polystyrene melts injected into an edge-gated circular cavity and a variable-gap-thickness cavity with an insert. The calculated results show very good agreement with the experimental results of the previous study by others in the position of the advancing melt fronts at each time step, weldline location, and pressure distributions.
    Additional Material: 15 Ill.
    Type of Medium: Electronic Resource
    Library Location Call Number Volume/Issue/Year Availability
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