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  • 1
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Macromolecules 23 (1990), S. 2261-2265 
    ISSN: 1520-5835
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Macromolecules 25 (1992), S. 4339-4344 
    ISSN: 1520-5835
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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  • 3
    ISSN: 1436-2449
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Summary In order to enhance the miscibility of poly(methyl methacrylate) and poly(butyl acrylate), pyridyl and carboxylic acid groups were introduced on the comonent polymer chains by free radical copolymerization. Differential scanning calorimetry shows that the blend of component polymers containing less than 10 mole% of carboxylic acid and pyridyl groups is immiscible, but the blend of more than 10 mole% become partially to completely miscible as the functionality increases. The chemical interaction between carboxylic acid and pyridyl group in the blend was manifested by a blue shift of 9 cm−1in the infrared stretching frequency of pyridyl group.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part B: Polymer Physics 29 (1991), S. 759-764 
    ISSN: 0887-6266
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The phase behavior of poly (ethylene oxide) (PEO) and poly(styrene-co-sodium sulfonated styrene) (SPS) blends has been examined as a function of copolymer composition. The mixtures show complex coacervation in dilute benzene/methanol (9/1, v/v) solution. The presence of intermolecular interactions between PEO and SPS in solution is verified by viscometry. Interaction between PEO and SPS in the solid state was supported by small-angle x-ray scattering; however, binary blends containing low PEO content show high miscibility, whereas the blends with high PEO content show phase separation.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part B: Polymer Physics 36 (1998), S. 2683-2689 
    ISSN: 0887-6266
    Keywords: interfacial tension ; square gradient theory ; equation-of-state theory ; polystyrene/poly(methyl methacrylate) blend ; polystyrene/poly(dimethyl siloxane) blend ; Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Interfacial tension between immiscible polymer pairs was predicted by using a square gradient theory in conjunction with the Flory-Orwoll-Vrij equation-of-state expression for the free energy of mixing. The contact interaction parameter was determined by fitting the equation-of-state theory to experimental cloud points taken from the literature, and the square gradient coefficient was estimated from the relation derived from a scattering function. The modified square gradient theory could successfully predict both the magnitude and temperature dependence of interfacial tension between polystyrene and poly(methyl methacrylate), although no adjustable parameters were used in calculating interfacial tension. The molecular weight dependence of interfacial tension was also successfully predicted. The contribution of free volume on interfacial tension is analyzed for two systems: polystyrene/poly(methyl methacrylate) and polystyrene/poly(dimethyl siloxane) blends. © 1998 John Wiley & Sons, Inc. J Polym Sci B: Polym Phys 36: 2683-2689, 1998
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 35 (1995), S. 1807-1810 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Blends prepared from poly(ethylene 2,6-naphthalate) (PEN) and poly(butylene 2,6-naphthalate) (PBN) show only partial miscibility judged from their glass transition temperatures. Two distinct mechanical behaviors are observed: brittle for the blends 〈 20 wt% of PBN, while ductile 〉 20 wt% of PBN. The experimental modulus and strength values of the blends are within the predicted values according to Kleiner and Paul models, respectively. This means that PEN/PBN blends are somewhat compatible based on their tensile properties. Especially for 20 wt% of PBN blend, the high modulus and strength are observed. The viscosity of the blend is high, which may imply a somewhat entangled morphology in the amorphous state.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    Journal of Chemical Technology AND Biotechnology 59 (1994), S. 365-370 
    ISSN: 0268-2575
    Keywords: penicillin G ; emulsion liquid membrane ; decomposition ; Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Process Engineering, Biotechnology, Nutrition Technology
    Notes: To confirm the applicability for the extraction of penicillin G by an emulsion liquid membrane (ELM), the degree of decomposition of penicillin G during extraction was theoretically calculated. Decomposition was less than 1% provided that the initial sodium carbonate concentration in the internal phase was correctly determined, which proved the applicability of the ELM process. The procedure to determine the initial carbonate concentration in the internal phase was also described in order that the pH in the internal phase should be within the relatively stable range for penicillin G at the end of the extraction.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    Journal of Chemical Technology AND Biotechnology 59 (1994), S. 371-376 
    ISSN: 0268-2575
    Keywords: penicillin G ; emulsion liquid membrane ; optimum extraction conditions ; Chemistry ; Biochemistry and Biotechnology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Process Engineering, Biotechnology, Nutrition Technology
    Notes: Penicillin G extraction by an emulsion liquid membrane (ELM) was investigated. The effects of surfactants, diluents, and carrier mixtures, together with their combined effects on the initial extraction rate and the emulsion stability were examined. Surfactants, diluents, and carriers used were Span80 (sorbitan monooleate)/ECA4360J (nonionic polyamine), n-butyl acetate/kerosene, and DOA (dioctylamine)/Amberlite LA-2 (secondary amine), respectively. The optimum extraction conditions were found to be 20% (v/v) of Span80 in ECA4360J as a surfactant, kerosene as a diluent and Amberlite LA-2 as a carrier.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
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