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  • 1
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 75 (1994), S. 6187-6189 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Slonczewski recently proposed a model for the exchange coupling between ferromagnetic layers separated by a nonferromagnetic spacer based on the concept of "loose spins.'' "Loose spins'' contribute to the total exchange energy. We have studied the role of "loose spins'' in bcc Fe/Cu/Fe(001) structures. bcc Fe/Cu/Fe(001) trilayers deposited at room temperature were investigated extensively in our previous studies. In our "loose spin'' studies, the Fe was added inside the Cu interlayer. Several structures were atomically engineered in order to test the behavior of "loose spins:'' One additional atomic layer of an (Fe+Cu) alloy were located in appropriate positions in a Cu spacer. The bilinear and biquadratic exchange coupling in the above structures was quantitatively studied with FMR in the temperature range 77–370 K and with MOKE at RT.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Iron-rich rare-earth (R) compounds, such as R2Fe17 do not show great potential for high-performance magnet materials due primarily to their low Curie temperatures (Tc∼300–400 K). However, relatively large quantities of nitrogen or carbon atoms can be introduced into the structure, resulting in a dramatic enhancement of magnetic properties including Tc (≥700 K). The N or C atoms cause a volume expansion of a few percent of the unit cell without changing the crystal structure. The large increase in Tc can be attributed to the volume dependence of the Fe–Fe exchange interactions. A large uniaxial anisotropy field develops for R=Sm upon nitriding/carbiding with an anisotropy field that is almost double the value for Nd2Fe14B at room temperature. Problems including the precipitation of soft magnetic phases (mainly α–Fe) and the limited thermal stability of the nitrides have so far restricted the applications of these compounds. Here data are presented on combined carbide/nitride alloys prepared using a novel technique. These alloys exhibit many of the advantages of the pure compounds but with greater thermal stability and less interference from precipitated phases. A typical material, Sm2Fe17(NxC1−x)3−δ has a Tc of 758 K and an anisotropy field (μ0HA) of 15 T at room temperature.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 73 (1993), S. 6038-6040 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Mössbauer studies were carried out at 77 K in two series of R2Fe17 compounds with a magnetic (Sm) and nonmagnetic (Y) rare-earth, intercalated with H, C, and N. The increase in hyperfine field is largest at the 12j(18f) sites for R2Fe17H3.7 and R2Fe17N2.3. While the lattice expansion in R2Fe17C2 is similar to that in the nitrides and hydrides, the small change in hyperfine fields at the 12j(18f) and 12k(18h) sites indicates that the presence of neighboring carbon largely cancels the moment increase associated with the volume increase. For R2Fe17 carbonitrides, a single, sharp magnetic transition indicates a uniform compound. However, Mössbauer spectra suggest the existence of both C-rich and N-rich precipitates in the carbonitrides whose average hyperfine fields and isomer shifts scale with the nitrogen to carbon ratio.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 75 (1994), S. 6181-6183 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The exchange coupling between iron layers separated by 11 monolayers (ML) of Cr(001) has been investigated using a structure in which the Cr(001) was grown on a bulk iron whisker Fe(001) surface at a temperature of approximately 300 °C. This temperature was selected to produce near optimum smoothness of the Cr layer. The Cr(001) deposition was followed by the deposition of 20 ML of Fe(001) at room temperature, and by the deposition of a 20 ML Au(001) protective layer. The frequencies corresponding to the magnetic excitations in this structure were measured by means of Brillouin light scattering (BLS). One of the observed frequencies corresponds to a surface mode in the bulk iron whisker. Another observed frequency corresponds to the lowest lying precessional mode of the magnetization in the 20 ML thick Fe(001) thin film. Typically, the thin film frequency exhibits a dependence on applied magnetic field that displays two cusps. The positions of the cusps are dependent on the exchange coupling between the 20 ML Fe film and the bulk iron substrate. The surface mode frequency increases monotonically with increasing field over most of the field range investigated. However, at the field corresponding to the low field cusp in the thin film frequency, the surface mode frequency undergoes an abrupt jump in magnitude. We have used the position of the cusps in the thin film data to deduce values for the bilinear, J1, and biquadratic, J2, coupling terms, where the coupling energy is written in the form EAB=−J1 cos(Δφ)+J2 cos2(Δφ); Δφ is the angle between the thin film and bulk iron magnetizations. Measurements of J1 and J2 have been carried out at six temperatures that span the range 100–350 K. Both J1 and J2 are found to depend strongly on temperature. The data are well described by the quadratic expression J2=−0.54+1.46 ×||J1||−0.52×J12, where J1 and J2 are expressed in erg/cm2. The large nonzero intercept and the linear term probably imply a significant intrinsic contribution to the biquadratic exchange.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 70 (1991), S. 6143-6145 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: A Mössbauer source technique has been used in studies of cobalt site preferences in the intermetallic compounds Er6Fe23 and Nd2Fe17. Data quality has been improved by the construction of a resonant conversion electron detector. This detector provides a tenfold increase in signal and allows measurements to be made with the source at reduced temperatures. Results for Er6Fe23 show a strong tendency for cobalt to occupy the f2 site and to avoid the f1 site. For Nd2Fe17, our results reveal that cobalt while it occupies preferentially the h and d sites, is almost completely absent from the c site, and it tends to avoid the f site.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 66 (1989), S. 768-771 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The glass formation, crystallization, and magnetic properties of (Fe1−xNdx)100−yBy (0.025≤x≤0.25, 5≤y≤20) have been investigated. Glass formation by melt spinning was found possible for Nd-Fe-B alloys with iron content less than 87.5 at. %. The thermal stability of ternary amorphous Nd-Fe-B alloys is proportional to boron concentrations, but is strongly dependent on Nd:Fe ratio as well. The strong increase of the crystallization temperature with additions of small amounts of neodymium to Fe-B can be attributed to the suppression of α-Fe formation upon crystallization. With increasing Nd:Fe ratio, the increase in Curie temperature with boron content is gradually diminished, and for Nd:Fe≥0.176 even a decrease of Curie temperature with increasing boron content is observed. Three metastable ternary structures were produced during the crystallization process.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 67 (1990), S. 4742-4746 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Extremely low doping levels (∼1 ppm) and unambiguous interpretation combine to make the Mössbauer-source technique an ideal method for determining cobalt site preferences in intermetallic compounds. Data on Gd2Fe17 and Nd2Fe14B are presented and compared with earlier work using Mössbauer spectroscopy, NMR, and neutron diffraction.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Review of Scientific Instruments 64 (1993), S. 679-682 
    ISSN: 1089-7623
    Source: AIP Digital Archive
    Topics: Physics , Electrical Engineering, Measurement and Control Technology
    Notes: A vibration-free conversion electron detector has been constructed for Mössbauer source experiments with extremely low doping levels (∼1 ppm) of cobalt-57. While the overall efficiency is somewhat less than that of microfoil systems, the design is greatly simplified and it still yields more than a sixfold enhancement in signal-to-noise ratio over standard transmission methods. The lightweight detector (∼25 g) may be mounted directly on a conventional transducer without limiting the performance. This allows low-temperature source measurements to be made by moving the detector and fixing the sample/source in a cryostat. The overall linewidth (HWHM) of the detector is 0.16 mm/s with the broadening being due to saturation effects in the enriched foil.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 70 (1991), S. 6006-6008 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Single phase alloys of composition RFe11Ti with R=Y, Sm, and Dy were prepared by induction melting. The samples were nitrided by thermal cycling to 770 K, at a heating rate of 10 K/min, under an atmosphere of nitrogen in a thermopiezic analyzer (TPA). For YFe11TiN the x-ray diffraction (XRD) patterns give a=0.8611 nm and c=0.4802 nm for the tetragonal structure, space group I4/mmm. This represents a 3% volume expansion of the nitrogen-free unit cell. The amount of absorbed nitrogen corresponds to one nitrogen atom per formula unit indicating that RFe11TiN is a true nitrogen compound with the nitrogen atoms occupying the 2b site in the structure. The expansion of the unit cell is accompanied by a dramatic increase in the Curie temperature for all compounds.
    Type of Medium: Electronic Resource
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  • 10
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 67 (1990), S. 4821-4823 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Fe100−xNdx amorphous ribbons were obtained for compositions with 25〈x〈50, and partially amorphous ribbons for all other compositions.The amorphous phases were magnetically ordered with Curie temperatures ranging from 421 to 493 K. During crystallization, three metastable phases (M1, M2, and M3) were formed. X-ray structural studies together with Mössbauer and thermomagnetic measurements suggest that the M1 phase is Fe23Nd6 (Mn23Th6 structure) with lattice parameter 1.152 nm and a Curie temperature of 515 K. The M2 phase is identified as Fe2Nd(Cu2Mg structure) with a lattice parameter of 0.745 nm and a Curie temperature of 567 K. The M1 and M2 phases transform to α-Fe and Nd2Fe17 at high temperatures (≥1000 K). The M3 phase is present in the as-quenched ribbons with x≥60 as well as in all crystallized ribbons. Structural data show that it is γ-Nd, an fcc form of Nd. All three nonequilibrium structures are high pressure phases which are often formed during rapid solidification and/or crystallization of amorphous phases.
    Type of Medium: Electronic Resource
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