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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Bulletin of volcanology 57 (1995), S. 185-196 
    ISSN: 1432-0819
    Keywords: Key words caldera ; carbonatite ; crater sediments ; fenitization ; Gross Brukkaros
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract  The Gross Brukkaros inselberg is a dome structure with a crater-shaped central depression within Precambrian/Cambrian country rocks which was active as a depocenter during the Late Cretaceous. The formation of the structure was due to the intrusion and subsequent intermittent depletion of a shallow magma reservoir. Juvenile material has not been recognized hitherto. This is the first account of juvenile lapilli from within the epiclastic fill of the caldera structure.The lapilli are calciocarbonatites and magnesiocarbonatites in composition, but are characteristically low in elements such as P, Nb, Ba and Sr, otherwise typical of carbonatites. This signature, however, is also characteristic of carbonatites from surrounding volcanic centers and necks. The Brukkaros sediments suffered strong metasomatic–hydrothermal alteration, which introduced in a first stage fluids rich in Fe, Ti, Na, Nb, V, K (Ca?, CO2?), and in a second stage the Brukkaros sediments were silicified on a large scale and locally enriched in P, Th and Cr. Si is derived from desilication of the wall rocks (basement?, Nama sediments) of the magma reservoir. Cr was probably mobilized during alteration of the abundant doleritic detritus within the Brukkaros depocenter.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Bulletin of volcanology 59 (1997), S. 1-9 
    ISSN: 1432-0819
    Keywords: Key words Carbonatite ; Diatreme ; Explosion ; Phreatomagmatism ; Root zone ; Gross Brukkaros
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract  Pipe G3b is part of the Upper Cretaceous carbonatitic Gross Brukkaros Volcanic Field in southern Namibia. The pipe represents the root zone of a diatreme and is located 2800 m west of the rim of Gross Brukkaros, a downsag caldera. The pipe is exposed approximately 550 m below the original Upper Cretaceous land surface. It cuts down into its own feeder dyke, 0.3 m thick. The pipe coalesced from two small pipes and in plan view is 19 m long and 12 m wide. It consists of fragmented Cambrian Nama quartzites and shales of the Fish River subgroup. Despite intensive brecciation, the stratigraphic sequence of the country rocks is almost preserved in the pipe. In addition, the feeder dyke became fragmented too and can be traced in a 2- to 3-m-wide zone full of carbonatite blocks along the southern margin of the pipe. The void space of the breccia is 30–50% in volume. Finally, after the disruption of country rocks and feeder dyke, a little carbonatite magma intruded some of the void space. The breccia of pipe G3b is considered to represent a root zone at the transition from the feeder dyke into a diatreme above. Formation of the breccia required a shock wave thought to have been associated with a last explosion of the diatreme immediately above the present level of exposure. The explosion can be shown to have been phreatomagmatic in origin.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    International journal of earth sciences 60 (1971), S. 924-948 
    ISSN: 1437-3262
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Description / Table of Contents: Abstract Volcanic breccias near an intrusive rhyolite dome in the Permian Saar-Nahe trough of southwest Germany have been identified as complex pipe-like subsidence-structures occupying the site and immediate neighbourhood of “explosive” volcanoes. At the Rödern, at first fine-grained, well-bedded and later coarser-grained and poorly bedded pyroclastic materials were deposited on top of a lava flow that formed the regional surface. Collapse along a ringfault with differential subsidence of 500 to 700 m produced a saucer-shaped structure in which steeply dipping pyroclastic beds still overlie the lava flow on which they were originally deposited. In the actual feeder, large blocks of country-rock subsided individually prior to wholesale subsidence of the entire feeder-content. Intrusion of a high alumina quartz tholeiite into the pyroclastic beds terminated the activity. The Hirschberg structure has essentially the same history, but is more fragmented. Subsidences vary between 150 and 260 m. Intrusion of petrographically and chemically similar basalt took place mainly near the margin of the ringfault. Three smaller structures also contain bedded pyroclastic deposits that subsided approximately 600, 1100, and 1400 m. The surface expressions of these five collapse structures are assumed to have been small collapse-calderas with diameters of several 100 m. to 1.5 km.
    Abstract: Résumé Aux alentours du «Donnersberg» dans la «Saar-Nahe-Senke» (Palatinat, Sudouest de l'Allemagne) des brèches volcaniques du Permien inférieur sont conservées à l'intérieur de structures d'effondrement. Celles-ci se trouvent au lieu mÊme de la cheminée originale et à ses alentours immédiats. Une de ces structures, le «Rödern», est caractérisée par des dépÔts pyroclastiques — fins à la base et plus grenus vers le sommet — couvrant des laves basaltiques à olivine. L'effondrement à l'intérieur d'une faille annulaire et une subsidence différentielle de 500 à 700 m ont eu comme résultat une structure rappelant un entonnoir. Les dépÔts pyroclastiques stratifiés reposent, quoiqu'avec un pendage fort, toujours en superposition normale et non faillés sur les basaltes à olivine qui eux aussi ont été affectés par la subsidence. A la cheminée mÊme on constate l'affaissement de grands panneaux de roches encaissantes suivi de l'effondrement de tout le remplissage de cheminée. L'activité s'achève par des venues d'une «high-alumina Quarz-Tholeiite». Le «Hirschberg», dont la structure et l'évolution ressemblent à celles du «Rödern», est caractérisé par une fragmentation du bloc effondré. L'affaissement de différents panneaux varie entre 150 et 260 m. Suite à la fragmentation de nouvelles venues basaltiques prennent place, soit le long de la faille annulaire, soit le long des failles entre les differents panneaux. Des dépÔts pyroclastiques stratifiés sont conservés encore dans trois autres structures plus petites. L'affaissement à l'intérieur de ces structures est de 600, 1100 et 1400 m au maximum Quant à la morphologie de la région après l'effondrement, on peut supposer qu'elle était caractérisée par l'existence de cratères profonds (caldères d'effondrement).
    Notes: Zusammenfassung Vulkanische Brekzien im Rotliegenden der Umgebung des Donnersberges in der Saar-Nahe-Senke/Pfalz liegen in Einbruchsstrukturen vor, die den ursprünglichen Schlot und seine unmittelbare Umgebung einnehmen. Am Rödern wurden ehemals auf einer Olivin-Basalt-Lava feinkörnige und spÄter grobkörnige Pyroclastica abgelagert. Einbruch an einem Ringbruch und differentielle Absenkung zwischen 500 und 700 m führte zur Anlage der trichterförmigen Struktur der geschichteten Pyroclastica. Trotz der Absenkung liegen sie immer noch mit ungestörtem Kontakt, jedoch nun steil einfallend, dem mitabgesenkten Olivin-Basalt auf. Am ursprünglichen Schlot ist Absenkung einzelner gro\er Nebengesteinsschollen und nachfolgend des gesamten Schlotinhaltes festzustellen. Die vulkanische AktivitÄt wurde durch Intrusion eines high-alumina Quarz-Tholeiites abgeschlossen. Der Hirschberg weist im wesentlichen die gleiche Struktur und Entwicklungsgeschichte auf, ist jedoch in mehrere Schollen untergliedert. Die BetrÄge der differentiellen Absenkung liegen zwischen 150 und 260 m. Infolge der Zerblockung innerhalb des Ringbruches intrudierte Basalt vorwiegend im Bereich der Verwerfungen, also am Ringbruch und zwischen einzelnen Schollen. Drei kleinere Strukturen enthalten ebenfalls geschichtete Pyroclastica und weisen maximale AbsenkungsbetrÄge von 600, 1100 und 1400 m auf. Im Bereich der ursprünglichen ErdoberflÄche müssen infolge der Einbrüche tiefe Krater vorgelegen haben, die als kleine Einbruchscalderen bezeichnet werden können.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Springer
    International journal of earth sciences 57 (1967), S. 189-198 
    ISSN: 1437-3262
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Description / Table of Contents: Abstract In the Lower Permian of the Saar-Nahe-Senke (Palatinate, SW Germany) several recently discovered volcanic necks have been investigated. In this preliminary report structure, composition, and age relationship of the breccias are described as well as their mode of emplacement which is believed to be due partly to fluidization and partly to calderalike subsidence of subaerially deposited tephra. In some of the necks magmatic intrusion terminated the volcanic activity. The volcanic neck of the Rödern is described as an example.
    Abstract: Résumé Plusieurs cheminées récemment découvertes dans le Permien inférieur des alentours du Donnersberg dans la Saar-Nahe-Senke (Palatinat, Sud-ouest d'Allemagne) ont été étudiées. Leur composition et les problèmes de l'âge et de la genèse sont discutés. Il faut distinguer des sédiments pyroclastiques des caldères d'effondrement et des brèches formées à l'intérieur des cheminées. Celles-ci se composent des lapillis et des fragments des roches encaissantes. Leur formation est le résultat d'un dégagement de gaz tenant en suspension des particules solides. La fin de l'activité est marquée en général par l'intrusion des laves. La cheminée du Rödern est décrite à titre d'exemple.
    Notes: Zusammenfassung Einige neuentdeckte Vulkanschlote im Rotliegenden der Umgebung des Donnersberges in der Saar-Nahe-Senke/Pfalz wurden hinsichtlich Aufbau, Alter und Genese untersucht. Es sind calderaartig abgesunkene Pyroclastica von Schlotbreccien zu unterscheiden, von denen Ablagerung aus einer Gas-Partikel-Suspension angenommen wird. Die Breccien setzen sich aus einer Mischung von Lapilli und z. T. aufgearbeitetem Nebengestein zusammen. In fast allen Schloten wurde die Aktivität durch das Eindringen von Schmelzen abgeschlossen. Als Beispiel wird der Schlot des Rödern beschrieben.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    [s.l.] : Nature Publishing Group
    Nature 262 (1976), S. 374-377 
    ISSN: 1476-4687
    Source: Nature Archives 1869 - 2009
    Topics: Biology , Chemistry and Pharmacology , Medicine , Natural Sciences in General , Physics
    Notes: [Auszug] Fig. 1 Schematic map of the South Europe plate and neighbouring plates for the late Hercynian time showing subplates, major wrench faults, and general structural trends within South Europe. Base map after Bullard et al.24 and Dewey et al.8. Thick lines = continental margins of bordering plates; ...
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  • 6
    Electronic Resource
    Electronic Resource
    Springer
    Bulletin of volcanology 57 (1995), S. 185-196 
    ISSN: 1432-0819
    Keywords: caldera ; carbonatite ; crater sediments ; fenitization ; Gross Brukkaros
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract The Gross Brukkaros inselberg is a dome structure with a crater-shaped central depression within Precambrian/Cambrian country rocks which was active as a depocenter during the Late Cretaceous. The formation of the structure was due to the intrusion and subsequent intermittent depletion of a shallow magma reservoir. Juvenile material has not been recognized hitherto. This is the first account of juvenile lapilli from within the epiclastic fill of the caldera structure. The lapilli are calciocarbonatites and magnesiocarbonatites in composition, but are characteristically low in elements such as P, Nb, Ba and Sr, otherwise typical of carbonatites. This signature, however, is also characteristic of carbonatites from surrounding volcanic centers and necks. The Brukkaros sediments suffered strong metasomatic-hydrothermal alteration, which introduced in a first stage fluids rich in Fe, Ti, Na, Nb, V, K (Ca?, CO2?), and in a second stage the Brukkaros sediments were silicified on a large scale and locally enriched in P, Th and Cr. Si is derived from desilication of the wall rocks (basement?, Nama sediments) of the magma reservoir. Cr was probably mobilized during alteration of the abundant doleritic detritus within the Brukkaros depocenter.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Springer
    Bulletin of volcanology 58 (1997), S. 421-431 
    ISSN: 1432-0819
    Keywords: Key words Carbonatite ; Dykes ; Diatremes ; Gross Brukkaros ; Phreatomagmatism ; Namibia
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract  In the Upper Cretaceous Gross Brukkaros Volcanic Field, southern Namibia, a radial dyke system surrounds a dome structure and its 74 closely related carbonatite diatremes. This paper focuses on volcanological features which seem to be typical for a low-viscosity melt in various settings such as dykes, sills and diatremes. The total or near absence of vesicles in carbonatite ash grains and lapilli inside the diatremes is evidence against explosive exsolution of volatile phases and in favour of a phreatomagmatic fragmentation mechanism and thus for a phreatomagmatic eruption mechanism of the carbonatite diatremes.
    Type of Medium: Electronic Resource
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  • 8
    ISSN: 1434-4475
    Keywords: Keywords. Silsesquioxanes; Organotin(IV) compounds; Mößbauer spectroscopy; Organohafnium(IV) compounds; X-Ray crystallography.
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Zusammenfassung.  Vier Komplexe von Silsesquioxanen mit Di- und Triorganozinn(IV)-Kationen wurden hergestellt; ihre Zusammensetzung wurde mit analytischen und spektroskopischen Standardmethoden bestimmt. Die Ergebnisse zeigen, daß in den gebildeten Komplexen Organozinneinheit und Ligand im Verhältnis von 1:1 vorhanden sind. FTIR-Spektren stehen im Einklang mit dem Auftreten von Sn*O-Schwingungen in den Verbindungen. Die Struktur der Komplexe wird auf der Grundlage von Mößbauer-Spektren und multinuklearen NMR-Experimenten (1H, 13C, 119Sn, 29Si) diskutiert. Ein Vergleich der experimentell beobachteten Quadrupolaufspaltung (QS) mit nach dem Konzept der partiellen Quadrupolaufspaltung (PQS) berechneten Werten ergab sowohl für die mit dem Dialkyzinn(IV)-Kation gebildeten Komplexe als auch für die Trialkylderivate eine regelmäßige tetraedrische Struktur. Ein neues Organohafniumsilsesquioxanderivat ([Cy 7Si7O12Hf(C5Me5)], Cy=Cyclohexyl, 5) wurde durch Umsetzung von [Cy 7Si7O9(OH)3] mit (C5Me5)HfMe3 unter Abspaltung von Methan hergestellt; seine Molekülstruktur wurde mittels Röntgenstrukturanalyse bestimmt.
    Notes: Summary.  Four complexes of silsesquioxanes with di- and triorganotin(IV) cations have been prepared; their composition was determined by standard analytical and spectroscopic methods. The results show that complexes containing an organotin(IV) moiety and the ligand in a 1:1 ratio are formed. FTIR spectra are consistent with the presence of Sn*O vibrations in the compounds. The structure of the complexes is discussed on the basis of Mößbauer and multinuclear (1H, 13C, 119Sn, and 29Si) NMR spectroscopic measurements. Comparison of the experimental quadrupole splitting (QS) with that calculated on the basis of the partial quadrupole splitting (PQS) concept revealed that the complexes formed with dialkyltin(IV) cations as well as the trialkyl derivatives have a regular tetrahedral structure. A new organohafnium silsesquioxane derivative ([Cy 7Si7O12Hf(C5Me5)], Cy=cyclohexyl, 5), was prepared by treatment of [Cy 7Si7O9(OH)3] with (C5Me5)HfMe3 under elimination of methane. The molecular structure of 5 was determined by X-ray crystallography.
    Type of Medium: Electronic Resource
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  • 9
    ISSN: 0044-8249
    Keywords: Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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  • 10
    ISSN: 0570-0833
    Keywords: Chemistry ; General Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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