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  • 1
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 73 (1993), S. 5890-5892 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: By means of x-ray phase analysis, it is shown that all the interstitial Sm2(Fe1−xAlx)17Ny nitrides and the parent compounds crystallize in Th2Zn17-type structure for x≤0.4. The lattice constants of the parent compounds increase linearly with Al concentration. The introduction of nitrogen leads to a further increase in lattice constants, but the amplitude of the increase decreases with increasing Al concentration. The introduction of nitrogen leads to an increase of Curie temperature Tc . The composition dependence of Tc of the parent compounds exhibits a maximum, whereas Tc of the nitride decreases monotonously with increasing Al concentration from 750 K for x=0 to 313 K for x=0.4. The mean magnetic moments of iron ions in both nitrides and parents decrease monotonously with increasing Al concentration.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 82 (1997), S. 5705-5710 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Polyfurfuryl alcohol (PFA) is pyrolyzed at 600 °C for different lengths of heat-treatment (HT) time (0–50 h) and at different pyrolytic temperatures (600–850 °C) for 4 h. Analysis by Raman spectroscopy shows that the crystallite size of PFA pyrolyzed at 600 °C decreases with increasing HT time. This suggestion is supported by the electrical conductivity measurements on PFA samples pyrolyzed at different HT temperatures and at 600 °C for different HT times. A trend of transition from semiconductive to metallic properties is suggested for the samples prepared above 850 °C. © 1997 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 3
    ISSN: 1862-0760
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract The rate-determining step of the intercalation and deintercalation process of lithium ions in LixNiO2 cathodes was studied by electrochemical impedance spectroscopic (EIS) analysis. EISs of the electrode process are composed of two semicircles. The higher frequency semicircle is related to the charge transfer resistance (Rct) and the double layer capacitance (Cdl), while the lower frequency semicircle results from ion incorporation impedance (Rlattice) and space charge capacitance (Csc). The assignment of the latter capacitance is discussed. It is found that Rlattice is 1000 times larger than Rct. Accordingly, in most cases the ion incorporation into the lattice dominates the kinetic behavior. But for the ideal hexagonal phase, in the deintercalated state the Warburg impedance becomes important. As a result, the ion diffusion in the lattice is the rate-determining step.
    Type of Medium: Electronic Resource
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