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  • 1
    ISSN: 1573-2932
    Keywords: Wet deposition ; emission sectors ; emission changes ; trend ; acidity ; long-range transport ; cloud level ; meteorological factors ; East-Germany
    Source: Springer Online Journal Archives 1860-2000
    Topics: Energy, Environment Protection, Nuclear Power Engineering
    Notes: Abstract Components in precipitation are dominantly dependent on structure and quantity of emissions on the course of the rainy air masses. It can be proved after meso-and long-range transport. Starting in 1982, precipitation is collected in 4-hour-periods at sites far from industry in East-Germany. For regions with specific geographical or uniform emission features arrival sectors are established, e. g. former GDR, Scandinavia, Poland, or Czech. The classification of the samples is done by back-trajectories. From the former GDR the anthropogenical components were most significantly raised before the political change, but acidity remained on an average level. After the change, the most emission products decline considerably —except NOX. Consequently, those lead to essential changes of pollutants in precipitation. The reduction is not uniformly. The report represents long-term data and discusses clear differences between components in deposition from sectors of the former GDR and West-Germany. The effects of atmospheric rehabilitation are analysed. Specially starting in 1993 the acidity of rain from the former GDR increases very strikingly up to now threefold more than from West-Germany (average ≤pH 4 at some sites). An explanation in terms of emission components only is devious, a complex consideration of change of dust composition as neutralizing factors and of processes of cloud formation and dispersal is necessary. It must be mentioned, that the acidity of precipitation from West-Germany and Scandinavia declines slightly in recent period. Therefore only sector-classified data show the real range of acidity.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 0930-7516
    Keywords: Chemistry ; Industrial Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The detailed dynamic simulation of coupled process units in chemical plants is gaining an increasing importance as a useful tool in plant engineering and operation. The outline of the program package DIVA (Dynamische Simulation verfahrenstechnischer Anlagen) which is currently under development is presented in the following. The dynamic plant equations and the corresponding Jacobian matrix are generated automatically. The full exploitation of sparse matrix techniques in combination with stiff ODE (ordinary differential equation) solvers allows an efficient solution of all the equations simultaneously. The possibilities offered by the simulator are demonstrated by the simulation of two laboratory plants.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Chemie Ingenieur Technik - CIT 67 (1995), S. 612-615 
    ISSN: 0009-286X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Chemie Ingenieur Technik - CIT 64 (1992), S. 25-40 
    ISSN: 0009-286X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Computer-aided generation of chemical engineering process models. The availability of adequate process models is still the most striking bottleneck for routine application of model-based techniques in process design and operation. The development of knowledge-based software tools to support process modeling is considered an important contribution to a solution of this problem. After a brief summary of the modeling tools offered in current simulator architectures, a future knowledge-based modeling tool is sketched. In addition to the software engineering, the acquisition and formalization of the modeling knowledge - comprising meaningful submodels and generic modeling strategies - is essential for the feasibility of the approach and for the acceptance of a tool. Therefore, these two themes are discussed in considerable detail. Finally, first prototype developments towards a knowledge-based modeling tool are presented.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Chemie Ingenieur Technik - CIT 70 (1998), S. 1132-1134 
    ISSN: 0009-286X
    Keywords: Chemistry ; Industrial Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Chemie Ingenieur Technik - CIT 71 (1999), S. 1119-1137 
    ISSN: 0009-286X
    Keywords: Chemistry ; Industrial Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: From Process Simulation to Lifecycle Modeling Process simulation is an established technology to support the design and operation of chemical processes. Since this technology has reached a mature state, an obvious question concerns emerging technologies which may succeed process simulation in the future. This contribution attempts to answer this question. The increasing capabilities of mathematical modeling and simulation on various levels of detail increasingly ask for the integration of available but independently developed and applied technologies across the process design lifecycle. Novel computer-based design support environments are required for this purpose. Such environments need to integrate existing modeling and simulation tools in a workflow oriented manner in order to provide context specific support during the whole design process.
    Additional Material: 15 Ill.
    Type of Medium: Electronic Resource
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  • 7
    ISSN: 0009-286X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Dynamic simulation of complex chemical processes. The detailed dynamic simulation of coupled process units in chemical plant is gaining increasing importance as an important tool in plant engineering and operation. This paper deals with basic problems in the development of a universally applicable dynamic simulator. General requirements are formulated. The program package DIVA currently under development is outlined. Simulation of the start-up phase of a simple production plant as an example demonstrates the mode of functioning and the potential of the simulator. Future work will concentrate on enlarging the model libraries and on increasing the efficiency and ease of use to meet the demands of industrial applications.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Berichte der deutschen chemischen Gesellschaft 89 (1956), S. 1119-1123 
    ISSN: 0009-2940
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Die Darstellung verschiedener Phosphorigsäureester des 3.4-Dihydroxy-toluols und des 2.2′ Dihydroxy-biphenyls wird beschrieben. Wasser übt auf den Verlauf der Reaktion zwischen Phosphortrichlorid und 3.4-Dihydroxy-toluol den gleichen katalytischen Einfluß aus wie auf die früher untersuchte Umsetzung mit Brenzcatechin. Dagegen wird das Verhalten von 2.2′-Dihydroxy-biphenyl gegenüber Phosphortrichlorid durch Wasser praktisch nicht beeinflußt.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Chemie Ingenieur Technik - CIT 61 (1989), S. 362-377 
    ISSN: 0009-286X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Wave propagation phenomena in chemical engineering processes. A phenomenological analysis of the dynamics of a number of different distributed parameter systems in chemical engineering reveals a surprisingly simple dynamic behaviour despite the complexity of the underlying nonlinear process models. Spatial structures or waves are propagating along a spatial coordinate during transients. The dynamics of most of the processes under consideration can be described with sufficient accuracy by three different model structures. These models serve as a basis for a theoretical system analysis. The investigation of characteristic properties of the propagating waves and the mechanisms responsible for wave formation are of central significance. Finally, it is shown how the extended knowledge about the processes may be applied for the solution of problems of technical interest.
    Additional Material: 20 Ill.
    Type of Medium: Electronic Resource
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  • 10
    Publication Date: 2014-02-26
    Description: In this work we present an approach for the sensitivity analysis of linearly-implicit differential-algebraic equation systems. Solutions for both, states and sensitivities are obtained by applying an extrapolated linearly implicit Euler discretization scheme. This approach is compared to the widely used sensitivity extensions of multi-step BDF methods by means of case studies. Especially, we point out the benefit of this method in the context of dynamic optimization using the sequential approach.
    Keywords: ddc:000
    Language: English
    Type: reportzib , doc-type:preprint
    Format: application/postscript
    Format: application/pdf
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