ISSN:
1042-7147
Keywords:
polyoxadiazoles
;
pendent imide groups
;
Chemistry
;
Polymer and Materials Science
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
Notes:
A series of new poly(1,3,4-oxadiazole-amide)s containing pendent imide groups has been synthesized by solution polycondensation of aromatic diamines containing preformed 1,3,4-oxadiazole rings with two diacid chlorides containing imide rings. These polymers were also prepared by the reaction of the same diacid chlorides with p-aminobenzhydrazide which were subsequently cyclodehydrated in solid state. The polymers were soluble in polar amidic solvents and some of them gave transparent flexible films by casting from solutions. They showed high thermal stability with decomposition temperatures above 400°C and glass transition temperatures in the range of 245-327°C. They had low dielectric constants, in the range of 3.32-3.94, and good tensile properties.
Additional Material:
5 Tab.
Type of Medium:
Electronic Resource
Permalink
