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  • 1
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    Macromolecules 28 (1995), S. 7022-7025 
    ISSN: 1520-5835
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Journal of materials science 33 (1998), S. 2629-2638 
    ISSN: 1573-4803
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract Changes to the Mode I interlaminar fracture toughness, GIc, and fracture mechanisms of stitched and unstitched fibreglass/vinyl ester composites were investigated after exposure to elevated temperatures. The fibreglass was stitched through the thickness with Kevlar®-49 thread in two orientations with two stitch densities, and then resin transfer moulded with a cold-curing vinyl ester resin. After curing at room temperature (∼20°C) for several weeks, the composites were heated to between 100 and 300°C for 1 h or at 175°C for times ranging from 0.25–100 h. The GIc values, which were measured using the double cantilever beam method, of stitched composites in the cold-cured condition were between 1.5 and 2.3 times higher than the unstitched composite. It was observed with scanning electron microscopy that this toughening occurred by deflection of the crack tip at the stitches, by the ability of the stitches to remain intact for a short distance (7–15 mm) behind the crack front, and by partial pull-out of broken stitches. The interlaminar fracture toughness of the unstitched composite increased slightly following heating, despite a possible breakdown of the chemical structure of the vinyl ester between 150 and 300°C. In contrast, the interlaminar toughness of the stitched composites was degraded significantly by heating, and this was probably caused by thermal deterioration of the Kevlar® stitches. This study reveals that the elevated-temperature post-curing of stitched composites will reduce the effectiveness of Kevlar® stitching in raising the Mode I interlaminar fracture toughness. © 1998 Chapman & Hall
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part B: Polymer Physics 34 (1996), S. 1133-1139 
    ISSN: 0887-6266
    Keywords: poly(p-phenylene vinylene) ; electrooptic Kerr effect ; molecular dynamics ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The molecular dynamics of p-phenylene vinylene (PPV) oligomers, synthesised by a condensation reaction and separated by molecular distillation, have been investigated using the electrooptic Kerr effect. The experimental Kerr constants of these materials change sign from positive to negative in going from n = 1 to n = 2 and are not in good agreement with theoretical results. The discrepancies, which increase in magnitude as n increases, can be attributed to solvent-solute interactions, the nonplanar nature of PPV oligomers, or the nonvalidity of the additivity scheme chosen for calculation of theoretical quantities. © 1996 John Wiley & Sons, Inc.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part B: Polymer Physics 36 (1998), S. 851-859 
    ISSN: 0887-6266
    Keywords: poly(aryl ether ketone)s ; dielectric relaxation spectroscopy ; dynamic mechanical analysis ; α-relaxation ; β-relaxation ; Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The relaxation behavior of four amorphous poly(aryl ether ketone)s was investigated using dielectric relaxation spectroscopy and dynamic mechanical analysis. The temperature dependence of the relaxation times of the glass transition process and the cooperative nature of this process were unaffected by changes in polymer structure. The temperature location of the loss peaks for all polymers progressed smoothly between the low frequency of the mechanical measurements and the higher frequencies of the dielectric probe. Differences were observed in mechanical activation energy and dielectric relaxation strength for one polymer which contained a significant concentration of meta linkages, compared with the para-linked polymers, while relaxation broadness was generally greater in the dynamic mechanical mode. Changes in chemical structure had little effect on the shape, intensity, and location of the β-relaxation peak, the main observation being that the Arrhenius activation energy measured by dynamic mechanical analysis was significantly higher than that calculated from the dielectric data. The dielectric β-relaxation was sensitive to absorbed moisture. © 1998 John Wiley & Sons, Inc. J Polym Sci B: Polym Phys 36: 851-859, 1998
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part B: Polymer Physics 36 (1998), S. 1465-1481 
    ISSN: 0887-6266
    Keywords: poly(phenylene) ; dielectric ; dynamic mechanical ; relaxation ; free volume ; positron annihilation ; Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The free volume and related mobility properties of substituted poly(p-phenylene) polymers are examined. The techniques used range from positron annihilation, dielectric relaxation, and dynamic mechanical spectroscopy to thermally stimulated currents. Fractional free volume is determined for the samples with different substituted side groups and related to the glass transition temperature. Bulkier groups lead to a greater fractional free volume and lower glass transition temperatures. Comparison of molecular relaxation times using the different characterization techniques demonstrates that there is strong coupling between motion of the main chain and the side groups, on which the dipoles reside. Intermolecular coupling between the main chains at the primary relaxation is shown in this work to be related to the nature of the side chains and resultant free volume, as are the temperature locations of local, secondary relaxations. A qualitative model describing the effect of regiochemistry on the motions and packing of these materials is also proposed. © 1998 John Wiley & Sons, Inc. J Polym Sci B: Polym Phys 36: 1465-1481, 1998
    Additional Material: 13 Ill.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part B: Polymer Physics 34 (1996), S. 2419-2431 
    ISSN: 0887-6266
    Keywords: dielectric relaxation ; thermoplastic blend ; coupling ; miscible blend ; polyester ; polycarbonate ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The dynamic mechanical and dielectric spectra of a miscible polyester and polycarbonate blend are investigated with emphasis on the latter technique. It was found that relaxation spectra for the blends from both techniques are broader than those of the constituent homopolymers. This is ascribed to greater intermolecular coupling and concentration fluctuations within the blends. The composition at which the greatest coupling occurs is dependent on the relaxation technique used and is skewed towards the component which shows the highest degree of intermolecular coupling. A number of parameters, such as relaxation time of the polymer molecules in the blend and relaxation strength, are compared as a function of reduced temperature (experimental temperature scaled by the glass transition temperature). Whereas blend behavior is generally intermediate between that of the homopolymers, it appears as though mobility of compositions with low polyester content have a greater relaxation time and possess a higher activation energy when compared to a simple, weighted average of the corresponding homopolymer values. © 1996 John Wiley & Sons, Inc.
    Additional Material: 13 Ill.
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part B: Polymer Physics 35 (1997), S. 1963-1971 
    ISSN: 0887-6266
    Keywords: dynamic mechanical analysis ; fluorinated poly(ethers) ; intermolecular cooperativity ; relaxation behavior ; Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The relaxation behavior of six fluorinated aromatic poly(ethers) was investigated using dynamic mechanical analysis. The glass transition temperature was found to increase as the size and rigidity of linking groups increased and varied between 168°C for a dimethyl linking group and 300°C for a bicyclic benzoate ether-linking group. For the α-relaxation the steepness of time/temperature plots and broadness of the loss curves could be qualitatively correlated with chemical structure in a manner predicted by the coupling model of relaxation. Well-separated sub-Tg transitions were also observed, as a shoulder on the low temperature side of the α-peak, and as a broad, low loss transition around -100°C. The higher temperature process was similar to the structural relaxation often found in quenched glassy polymers, while the position, intensity, and breadth of the subambient process was sensitive to chemical structure. © 1997 John Wiley & Sons, Inc. J Polym Sci B: Polym Phys 35: 1963-1971, 1997
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
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