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  • 1
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    The @journal of physical chemistry 〈Washington, DC〉 89 (1985), S. 2013-2019 
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 0142-2421
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Physics
    Notes: Silicon oxynitride (SiOx Ny) thin films were deposited on silicon substrates by ion-assisted deposition. Variable angle spectroscopic ellipsometry (VASE) was used to optically characterize the deposited film properties, such as layer thickness and composition, film surface and interface qualities, as well as the retractive index spectrum in the wavelength range 320-820 nm. The measured VASE spectra were analyzed by assuming SiOx Ny to be a physical mixture of two distinct phases, silicon dioxide and silicon nitride, using the Bruggeman effective medium approximation. Remarkably good agreements between the measured spectra and model calculations were obtained over the entire spectral range for all the samples studied. Layer thicknesses of SiOx Ny films determined by VASE were consistent with their corresponding nominal values. The ellipsometrically deduced refractive index spectrum was observed to be strongly dependent on the film composition. In addition, the film refractive index at each applied wavelength was found to be a linear function of its constituent relative volume fraction. The results from VASE analysis also indicated that all the sample films investigated exhibited smooth surfaces, sharp interfaces between the film and substrate and high packing density.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    International Journal of Chemical Kinetics 18 (1986), S. 363-378 
    ISSN: 0538-8066
    Keywords: Chemistry ; Physical Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The pyrolysis of ethylbenzene has been investigated in shock waves with the laser schlieren technique. Mixtures of 1 and 2% ethylbenzene in krypton were studied for reaction conditions of 1300-1800 K, 70-550 torr. At high temperatures, the initial rapid endothermic dissociation is followed by a region of net exothermic reaction, which is readily understood as arising mainly from methyl radical recombination after dissociation to methyl and benzyl radicals. The initial unimolecular dissociation rates show no detectable dependence on pressure; with ΔH0298 = 75.7 kcal mol-1 these rates are \documentclass{article}\pagestyle{empty}\begin{document}$$ \log k({\rm s}^{{\rm - 1}}) = 13.49 - 60.0/\theta $$\end{document} An RRKM extrapolation suggests \documentclass{article}\pagestyle{empty}\begin{document}$$ \log k_\infty ({\rm s}^{{\rm - 1}}) = (15.95 \pm 0.3) - (74.7 \pm 2)/\theta $$\end{document} in excellent agreement with previous lower temperature data.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
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