ISSN:
1662-8985
Source:
Scientific.Net: Materials Science & Technology / Trans Tech Publications Archiv 1984-2008
Topics:
Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
Notes:
The inorganic and organic hybrid compound, [O=VPd(2-Pyd-)4]n (2-Pyd- = 2-pyridonate)(1), was synthesized by assembling its monomer units in the organic solution. X-ray absorptionspectroscopic (XAFS) studies indicated that oxidation states of the vanadium and palladium ions in 1were +IV and +II, and the distance between them was estimated to be 2.698-2.700 Å. Scanningelectron microscope (SEM) observation revealed that the compound 1 shapes in long columnarcrystals with micrometer-sized cross section. EXAFS and IR studies suggested that the O=V oxygenatom interacted to the central palladium ion in the neighboring monomer unit, forming the inorganicinfinite chain structure, -(O=V-Pd)n-, in the columnar crystals of 1
Type of Medium:
Electronic Resource
URL:
http://www.tib-hannover.de/fulltexts/2011/0528/01/39/transtech_doi~10.4028%252Fwww.scientific.net%252FAMR.11-12.273.pdf
Permalink