ISSN:
0018-019X
Keywords:
Chemistry
;
Organic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Volumes of activation for the base hydrolysis of the dichromate anion have been measured at 298.2 K, using high-pressure stopped-flow spectrophotometry. The values of ΔV* (cm3 · mol-1), - 17.9 ± 0.6, - 19.2 ± 0.9, - 24.9 ± 0.9 and - 26.0 ± 0.7 for OH-, NH3, H2O and 2,6-lutidine, respectively, are consistent with an interchange mechanism with associative activation mode (Ia).
Additional Material:
3 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/hlca.19830660809
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