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  • 1
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Physics Edition 17 (1979), S. 531-534 
    ISSN: 0098-1273
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 11 (1971), S. 99-108 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: An experimental procedure is outlined to examine the potential of thermoplastic sheets in draw forming. Experiments carried out on a variety of materials indicate that the following requirements must be fulfilled for a thermoplastic sheet to be cold formable: (1) The glass transition of polymer should be above ambient temperature and above the temperature of forming, (2) tensile elongation at break should equal or exceed 30%, (3) ratio of tensile to compressive yield stress should equal or exceed 1.6 and (4) sheet must not yield locally (neck) when strained in tension.An experimental method has been developed to determine the compressive, friction and bending forces which oppose the drawing force exerted by the punch. It is shown that the compressive force is, in most cases, largest. A stress analysis is carried out leading to an expression correlating the maximum depth of draw as a function of basic properties of sheets such as tensile strength (St*) and compressive yield stress (Sc). The effect of rolling on drawability is examined and interpreted in terms of the ratio St*/Sc. The cold formed items have a lower heat distortion temperature than their thermoformed counterparts.
    Additional Material: 13 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 5 (1965), S. 152-158 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: An explanation is presented to account for the deterioration of the mechanical properties at very low concentrations of absorbed oxygen. The induction time as measured by the oxygen absorption technique overestimates the time to failure with respect to the mechanical properties. Furthermore, it is shown that the extrapolation of accelerated aging data as obtained at elevated temperatures should not be carried out below 50°C. Data are presented to show that an anti-oxidant is one of the major constituents of a stabilizer system against UV radiation, because the oxidative degradation mechanism is involved. A modified oxygen uptake equipment is described which allows the simultaneous determination of the oxygen absorption and the deterioration of the mechanical properties on the same sample.
    Additional Material: 18 Ill.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 11 (1971), S. 109-123 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The problems encountered with cold formed thermoplastic material, namely, low heat distortion temperature and stress and solvent crazing, can be overcome by using a laminate consisting of a reinforced thermosetting core sandwiched between two drawable face sheets. This process imposes a restriction on the material by the need for a curing cycle to transform the core into a hard, three dimensional network. To take full advantage of the very fast metal forming technique, the curing should be accomplished outside of the forming apparatus and without external restraint. In order to impart a practical shelf life to the laminate at room temperature, the chemical requirements of the core can only be met with an elevated temperature cure. This in turn places an additional restriction on the face sheets, as they will have to withstand the curing conditions without external constraint and without dimensional changes of the formed part. Finally, the face sheets then have to become an integral part of the formed laminate upon curing of the latter, involving a high adhesive strength between the cured core and the face sheets. The criteria for the selection of the materials for various layers are presented as well as the limitations on the construction of the entire laminate.
    Additional Material: 22 Ill.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 3 (1963), S. 168-175 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Resin structures available from chlorinated polyethylene have been determined by studies of the infrared absorption spectra, and have been related to the glass transition temperatures and degree of crystallinity of the products. The relationships between chlorine content, molecular weight, glass transition temperature and a number of mechanical and rheological properties are described. Data are presented on the effect of blends of various resins in this series on glass transition phenomena. The stability of the resins to dehydrochlorination is discussed.
    Additional Material: 20 Ill.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 13 (1969), S. 2689-2697 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: High molecular weight linear polyethylene has been irradiated in the solid state by high energy electrons. The irradiated samples were characterized by differential scanning calorimetry, solubility properties, and stress-strain measurements. A failure mechanism is proposed for the observed embrittlement of the polymer.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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