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  • 1
    ISSN: 1432-1866
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract To divulge plausible source for fluorine in the Upper Ladinian of the East Alpine geosyncline, two totally independent geochemical approaches have been made. They are (i) correlation study of the stratabound, stratiform, paleographic and regional fluorine anomalies observed in seven selected profiles of the carbonate sequences and (ii) comparative study of the distribution of rare earths (REE) in fluorspars from northern and southern Ladinian sequences. The fluorine anomalies in the entire East Alpine geosyncline were found to be confined only to a few horizons which could be stratigraphically correlated. The fluorspars of the Nördliche Kalkalpen showed REE distribution characteristic of a sedimentary formation while those of the Südliche Kalkalpen (Bleiberg area) apparently showed a hydrothermal type of REE distribution. These and various other considerations discussed in the present paper go to show that a relatively short-termed submarine exhalative source (volcanic) of a recurring nature in the Ladinian stage of the Mid-Triassic might have been plausibly responsible for the supply of fluorine found in the carbonate sequences of the East Alpine geosynclines. The noted stratigraphic correlation of fluorine anomalies suggested, in addition, that fluorine bearing layers could be used as temporaneous marker beds. An interesting side observation was that of the bi-to tri-modal fluorine distribution in four profiles which represented well mineralized areas in contrast to the unimodal fluorine distribution in the rest three profiles with no distinct zone of mineralization. Probably such a multimodal distribution of fluorine may be characteristic of the Pb-Zn deposits (or other ore bearing-units) in paragenesis, granted which, it may find application as proximity indicators of ore deposits.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Mineralium deposita 11 (1976), S. 111-116 
    ISSN: 1432-1866
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract A comprehensive review of the authors' and their co-workers' results on the fractionation of Rare Earth Elements (REE) during the crystallization and/or recrystallization of Fluorspar is given. The fractionation can be explained as the result of REE complexation in the ore forming solution and systematic changes in distribution coefficients of REE. It is shown that the Tb/Ca and Tb/La ratios are sufficient to characterize pegmatitic (pneumatolytic), hydrothermal and sedimentary fluorspar. This has been confirmed by numerous investigations on various types of deposits.
    Type of Medium: Electronic Resource
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  • 3
    ISSN: 1432-1866
    Source: Springer Online Journal Archives 1860-2000
    Topics: Geosciences
    Notes: Abstract Controversial genetical interpretations on the fluorite occurrences in the leadzinc deposits of the Nördliche Kalkalpen led to the present study. The distribution of the rare-earth elements (REE) in the fluorspar-carbonate assemblages and the fluorspar separates have been determined non-destructively by means of instrumental neutron activation analysis using high resolution γ-spectrometry. A geochemical model describing the distribution of the REE in the two mineral phases of CaCO3 and CaF2 formed syngenetically under marine conditions has been built up in order to elucidate the observed REE abundances in the carbonates and their fluorspar separates. The low and comparable concentrations of REE, the similarity in their relative distribution patterns in carbonate-fluorspar assemblages as compared to those in carbonate sediments observed by other authors and the sedimentary characterization via the Tb/Ca-Tb/La relation criterion revealed by the present study unequivocally suggest a synsedimentary nature of the fluorspar. In addition, the study showed that a diagenetic recrystallization results in a further fractionation of Tb and La with a preferential improverishment in La. Such a phenomenon opens a possible geochemical criterion for the identification of different generations of fluorspars.
    Type of Medium: Electronic Resource
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