Library

X
feed icon rss

Your email was sent successfully. Check your inbox.

An error occurred while sending the email. Please try again.

Proceed reservation?

Export
  • 1
    Electronic Resource
    Electronic Resource
    Synthesis and Characterization of Oxotechnetium(V) Complexes with Aza-Substituted 2,6-Dimethyl-4-azaheptane-2,6-dithiol Ligands and Benzyl Mercaptan as Coligand (1995)
    s.l. : American Chemical Society
    Inorganic chemistry 34 (1995), S. 1077-1082 
    Details
    ISSN: 1520-510X
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1021/ic00109a013
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 2
    Electronic Resource
    Electronic Resource
    Synthesis, Characterization, and X-ray Study of a Heteroleptic Samarium(III) Porphyrin Double Decker Complex (1995)
    s.l. : American Chemical Society
    Inorganic chemistry 34 (1995), S. 2476-2479 
    Details
    ISSN: 1520-510X
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1021/ic00113a035
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 3
    Electronic Resource
    Electronic Resource
    2-Acetylpyridinium 4N-Phenylthiosemicarbazone Chloride 1.25-Hydrate (1996)
    Oxford [u.a.] : International Union of Crystallography (IUCr)
    Acta crystallographica 52 (1996), S. 2027-2029 
    Details
    ISSN: 1600-5759
    Source: Crystallography Journals Online : IUCR Backfile Archive 1948-2001
    Topics: Chemistry and Pharmacology , Geosciences , Physics
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1107/S010827019600176X
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 4
    Electronic Resource
    Electronic Resource
    An Unusual Hydrogen-Bonded Network Associated with Metal-Organic Chains: Structure and Crystal Packing of the Coordination Polymer [Cd(terephthalate)(H2O)3].4H2O (1998)
    Copenhagen : International Union of Crystallography (IUCr)
    Acta crystallographica 54 (1998), S. 657-662 
    Details
    ISSN: 1600-5740
    Source: Crystallography Journals Online : IUCR Backfile Archive 1948-2001
    Topics: Chemistry and Pharmacology , Geosciences , Physics
    Notes: Single crystals of [Cd(terephthalate)(H2O)3].4H2O (1), triaquo(1,4-benzenecarboxylato-κO)cadmium tetrahydrate, are grown in a silica gel column. Crystal structure analysis shows that (1) is a polymer with metal-organic chains stacked along the a axis forming layers parallel to the ab plane. These layers are linked by an unusual hydrogen-bonded network formed by the water molecules (both `free' and coordinated ones) and the carboxylate O atoms. This network comprises tridymite-like O8 cages which `propagate' in the direction of the a axis, mimicking the way they `propagate' along the c axis in hexagonal ice.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1107/S0108768197020107
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 5
    Electronic Resource
    Electronic Resource
    Synthesis, spectroscopic, and structural characterization of the first aqueous cobalt(II)-citrate complex: toward a potentially bioavailable form of cobalt in biologically relevant fluids (2000)
    Springer
    JBIC 5 (2000), S. 469-474 
    Details
    ISSN: 1432-1327
    Keywords: Key words Cobalt-citrate complex ; Speciation ; Structure ; Electron paramagnetic resonance ; Bioavailability
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Chemistry and Pharmacology
    Notes: Abstract Citric acid represents a class of carboxylic acids present in biological fluids and playing key roles in biochemical processes in bacteria and humans. Its ability to promote diverse coordination chemistries in aqueous media, in the presence of metal ions known to act as trace elements in human metabolism, earmarks its involvement in a number of physiological functions. Cobalt is known to be a central element of metabolically important biomolecules, such as B12, and therefore its biospeciation in biological fluids constitutes a theme worthy of chemical and biological perusal. In an effort to unravel the aqueous chemistry of cobalt in the presence of a physiologically relevant ligand, citrate, the first aqueous, soluble, mononuclear complex has been synthesized and isolated from reaction mixtures containing Co(II) and citrate in a 1 :2 molar ratio at pH∼8. The crystalline compound (NH4)4[Co(C6H5O7)2] (1) has been characterized spectroscopically (UV/vis, EPR) and crystallographically. Its X-ray structure consists of a distorted octahedral anion with two citrate ligands fulfilling the coordination requirements of the Co(II) ion. The magnetic susceptibility measurements of 1 in the range from 6 to 295 K are consistent with a high-spin complex containing Co(II) with a ground state S=3/2. Corroborating this result is the EPR spectrum of 1, which shows a signal consistent with the presence of a Co(II) system. The spectroscopic and structural properties of the complex signify its potential biological relevance and participation in speciation patterns arising under conditions consistent with those employed for its synthesis and isolation.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/s007750050007
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 6
    Electronic Resource
    Electronic Resource
    Synthesis and X-ray crystal structure of [1,3-bis(η5-cyclopentadienyl)-1,1,3,3-tetramethyldisiloxane]hafnium(IV) dichloride (1997)
    Springer
    Monatshefte für Chemie 128 (1997), S. 961-967 
    Details
    ISSN: 1434-4475
    Keywords: Hafnium ; Cyclopentadienyl ; ansa-Metallocenes ; X-ray analysis
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Zusammenfassung Der tetramethyldisiloxan-überbrückte Hafnocenkomplex [HfCl2{μ-(η5-C5H4)-SiMe2OSiMe2(η2-C5H4)}] (1) wurde durch Umsetzung von HfCl4 mit dem lithiiertenBis(cyclopentadienyl)disiloxan (LiC5H4SiMe2)2O im Molverhältnis 1:2 dargestellt. Die neue Verbindung wurde spektroskopisch und röntgenographisch charakterisiert. Sie kristallisiert in der monoklinen RaumgruppeP21/c und ist isostrukturell mit den entsprechenden Titan-und Zirkoniumkomplexen. Die Dimensionen der Einheitszelle sinda=13.51(1) Å,b=8.672(7) Å,c=15.41(1) Å, β=97.15(2)° undZ=4.
    Notes: Summary The tetramethyldisiloxane-bridged hafnocene complex [HfCl2{μ-(η5-C5H4)SiMe2OSiMe2(η2-C5H4)}] (1) has been prepared by the reaction of HfCl4 with the dilithiatedbis(cyclopentadienyl)disiloxane (LiC5H4SiMe2)2O in a molar ratio of 1:2. The new compound was characterized by spectroscopic and X-ray diffraction methods. The crystals are monoclinic of space groupP21/c and isostructural with the corresponding complexes of titanium and zirconium. The unit cell dimensions area=13.51(1) Å,b=8.672(7) Å,c=15.41(1) Å, β=97.15(2)°, andZ=4.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00806962
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 7
    Electronic Resource
    Electronic Resource
    New [Ti(η5-C5H5)Cl2(OR)] complexes. Crystal and molecular structure of η5-Cyclopentadienyl(cyclohexoxy)titanium(IV) dichloride (1996)
    Springer
    Monatshefte für Chemie 127 (1996), S. 1137-1143 
    Details
    ISSN: 1434-4475
    Keywords: Titanium ; Cyclopentadienyl ; Akloxytitanium complexes ; X-ray analysis
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Zusammenfassung Durch Umsetzung von [Ti(η5-C5H5)Cl3] mit dem geeigneten Alkohol wurde eine Reihe von neuen Verbindungen der Formel [Ti(η5-C5H5)(OR)] (R=C6H11 (cyclohexyl,1), CH2CH(CH3)2 (2), CH(C2H5)2 (3) und CH2C6H5 (4)) erhalten. Alle Komplexe wurden elementaranalytisch sowie IR- und1H-NMR-spektroskopisch charakterisiert. Die Struktur von1 wurde röntgenographisch bestimmt; Kristalldaten: triklin,a=11.334(2),b=13.590(2),c=12.237(2) Å, α=113.501(5), β=118.182(5), γ=101.993(6),V=1328.2(4) Å3,T=298K, Raumgruppe P1,Z=4, zwei kristallographisch unabhängige Moleküle in der Elementarzelle; abschließendeR-Werte:R=0.0583 undR w=0.0632. Verbindung1 zeigt überraschend kurze Ti-Cl- und Ti-O-Abstände; dies deutet auf eine starke π-Elektronendonorwirkung des Chlorid- und vor allem des Alkoxidliganden hin. Der Ti-O-C-Bindungswinkel ist ungewöhnlich groß.
    Notes: Summary A series of new compounds with molecular formula [Ti(η5-C5H5)Cl2(OR)] (R=C6H11 (cyclohexyl,1), CH2CH(CH3)2 (2), CH(C2H5)2 (3), and CH2C6H5 (4)) has been obtained by the reaction of [Ti(η5-C5H5)Cl3] with the appropriate alcohol. All complexes were characterized by elemental analysis and by IR and1H NMR spectroscopy. The structure of1 was determined by X-ray diffraction studies; crystal data: triclinic,a=11.334(2),b=13.590(2),c=12.237(2) Å, α=113.501(5), β=118.182(5), γ=101.993(6),V=1328.2(4) Å3,T=298K, space P1,Z=4, two crystallographically independent molecules in the unit cell. FinalR andR w values are 0.0583 and 0.0632, respectively. Compound1 exhibits surprisingly short Ti-Cl and Ti-O distances, suggesting strong π donation by the chloride and in particular by the alkoxide ligand. The Ti-O-C angle is unusually large.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00844688
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 8
    Electronic Resource
    Electronic Resource
    Reaction of titanocene dihalides with Na2H2 EDTA. Crystal structure of [Ti(EDTA)(H2O)] (1997)
    Springer
    Monatshefte für Chemie 128 (1997), S. 1201-1206 
    Details
    ISSN: 1434-4475
    Keywords: Titanium ; EDTA ; Crystal structure ; Sevenfold coordination
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Zusammenfassung Titanocenkomplexe ([Ti(η5-C5H4 R)2 X 2];R=H, SiMe3;X=Cl, Br) reagieren in wäßrigem Methanol mit Na2H2 EDTA unter Verdrängung der Halogen- und Cyclopentadienylliganden zum selben Produkt ([Ti(EDTA)(H2O)]). Die Struktur von ([Ti(EDTA)(H2O)]) wurde röntgenographisch bestimmt. Kristalldaten: monoklin,a=13.923(6),b=7.048(3),c=13.252(5) Å, β=90.81(1)°, RaumgruppeP21/c,Z=4. In diesem Komplex ist das Titanatom mit einem sechszähnigenEDTA-Liganden und einem Wassermolekül, das eine zusätzliche Koordinationsstelle besetzt, siebenfach koordiniert.
    Notes: Summary Titanocene complexes ([Ti(η5-C5H4 R)2 X 2];R = H, SiMe3;X=Cl, Br) react with Na2H2 EDTA in aqueous methanol to give an identical product ([Ti(EDTA)(H2O)] by cleavage of the halogen and cyclopentadienyl ligands. The structure of [Ti(EDTA)(H2O)] has been determined by X-ray diffraction; crystal data: monoclinica=13.923(6),b=7.048(3),c=13.252(5) Å, β=90.81(1)°, space groupP21/c,Z=4. In this complex, Ti has a sevenfold coordination with a hexadentateEDTA 4− ligand and a water molecule occupying an additional coordination site.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1007/BF00807251
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 9
    Electronic Resource
    Electronic Resource
    Sulfur-Selenium Chelates: Crystal structure of the first titanocene derivative Ti(η5-C5H5)2SSe4 (1995)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 621 (1995), S. 1800-1802 
    Details
    ISSN: 0044-2313
    Keywords: Titanocene sulfidotetraselenides ; Selenium-sulfur chelates ; X-ray analysis ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Schwefel-Selen Chelate: Kristallstruktur des ersten Titanocenderivats Ti(η5-C5H5)2SSe4Die Kristallstruktur von Bis(→5-cyclopentadientyl)titana(TiIV)-thiacyclohexaselenan, Ti(η5-C5H5)2SSe4 (1) wurde durch Röntgenstrukturanalyse bestimmt. (1) kristallisiert monoklin in der Raumgruppe P21/c, Z = 4, a = 13,179, b = 8,087, c = 14,447 Å, β = 114,857°. Der sechsgliedrige Heterocyclus TiSSe4 hat die erwartete Sesselkonformation. Im Chelatring ist das Ti-Atom and S und Se gebunden. Die Geometrie von (1) stimmt sehr gut mit der von Ti(η5-C5H5)2Se5 überein.
    Notes: The crystal structure of bis(η5-cyclopentadienyl)titana(TiIV)-thiacyclohexaselenane, Ti(η5-C5H5)2SSe4 (1), has been determined by X-ray diffraction data. (1) crystallizes in the monoclinic space group P21/c with four formula units in the unit cell. The cell dimensions are a = 13.179, b = 8.087, c = 14.447 Å, β = 114.857°. The six-membered heterocycle TiSSe4 has the expected chair conformation. In the chelate ring the Ti atom is S- and Se-bonded. The geometry of (1) corresponds closely to that of Ti(→5-C5H5)2Se5.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/zaac.19956211032
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 10
    Electronic Resource
    Electronic Resource
    Synthesis, characterization, and structures of New Titanocene Isoselenocyanato Complexes (1996)
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 622 (1996), S. 1387-1391 
    Details
    ISSN: 0044-2313
    Keywords: Titanium ; Metallocene ; Isoselenocyanate ; Crystal Structure ; Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Darstellung, Charakterisierung und Strukturen von neuen Titanocen-isoselenocyanat KomplexenDie Komplexe [Ti(η5-C5H4R)2(NCSe)2] [R = Me (1), SiMe3 (2) oder SiEt3 (3)] wurden durch Umsetzung der entsprechenden Dichloride mit KSeCN dargestellt; der sauerstoffverbrückte Komplex [Ti(η5-C5H4R)2(NCSe)]2O (4) entsand durch Luftoxidation von (1). Alle Komplexe wurden elementaranalytisch sowie IR-, 1H-NMR- und massenspektroskopisch charakterisiert. Die Röntgenstrukturanalysen von (1) und (4) bestätigen die IR-Ergebnisse, daß diese Komplexe N-gebundene Selenocyanat-liganden enthalten. Die Geometrie um Titan ist pseudotetraedrisch. Die Ketten N—C—Se sind linear mit normalen N—C und C—Se Bindungsabständen. Das Dimer enthält eine annähernd lineare Ti—O—Ti Brücke (Bindungswinkel 173,4º) mit einem Ti—O-Abstand von 1,838 Å. Die Strukturergebnisse werden mit denen analoger Verbindungen verglichen.
    Notes: The complexes [Ti(η5-C5H4R)2(NCSe)2] [R = Me (1), SiMe3 (2), or SiEt3 (3)] were prepared from the corresponding dichlorides with KSeCN in acetone; the oxygen-bridged complex [Ti(η5-C5H4Me)2(NCSe)]2O (4) was formed by air oxidation of (1). All complexes were characterized by elemental microanalysis and by IR, 1H NMR, and mass spectroscopies. An X-ray analysis of (1) and (4) confirms the results of IR studies that these complexes contain N-bonded selenocyanate ligands. In molecules (1) and (4) there is a pseudotetrahedral arrangement about each titanium. The N—C—Se chains are linear with normal N—C and C—Se bond distances. The dimer (4) contains an approximately linear Ti—O—Ti bridge (angle 173.4º) with a Ti—O bond distance of 1.838 Å. The structural results are compared with those in related compounds.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/zaac.19966220818
    Library Location Call Number Volume/Issue/Year Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
Close ⊗
This website uses cookies and the analysis tool Matomo. More information can be found here...