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  • 1
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 69 (1996), S. 497-499 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Diamond crystallites up to 40 nm in size have been grown from a highly ionized plasma beam of acetylene for ion energies close to 100 eV per C atom and substrate temperatures above 450 °C. This shows that diamond can be grown by physical vapor deposition from an ion-rich plasma as well as by chemical vapor deposition from a radical-rich plasma. The formation mechanism is argued to be one of nucleation and growth rather than a stress induced transformation from graphite. © 1996 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 68 (1996), S. 909-911 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Cubic boron nitride (c-BN) thin films have been deposited by unbalanced rf (13.56 MHz) magnetron sputtering of a hexagonal boron nitride target in a pure argon discharge. Deposition parameters have been 300 W rf target power, 8×10−4 mbar argon pressure, 3.5 cm target substrate distance, and 800 K substrate temperature. Under these conditions the ion current density is 2.25 mA/cm2 and the growth rate is ∼1.1 A(ring)/s. By applying a rf substrate bias the ion plating energy is varied from plasma potential of 37 eV up to 127 eV. The films have been characterized by infrared (IR) and Auger electron spectroscopy (AES), x-ray diffraction (XRD), x-ray reflectivity, elastic recoil detection (ERD), Rutherford backscattering (RBS), nuclear resonance analysis (NRA), and stress measurements. The subplantation model proposed by Lifshitz and Robertson can be applied to the c-BN formation. An energy of about 85±5 eV is found where the stress (25 GPa, 200 nm film thickness) and the c-BN content ((approximately-greater-than)90%) have a maximum. The grain size of the crystalline c-BN phase was estimated to be in the range of 5 nm. Below an energy of 67±5 eV no c-BN could be detected. An excellent adhesion has been obtained by a special interface treatment. © 1996 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 65 (1994), S. 2588-2590 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The influence of the plasma excitation frequency on the growth conditions and the material properties of microcrystalline silicon prepared by plasma enhanced chemical vapor deposition at low deposition temperature is investigated. It is found that an increase of the plasma excitation frequency leads to a simultaneous increase of the growth rate, the grain size, and the Hall mobility of microcrystalline silicon. This is attributed to an effective selective etching of disordered material creating more space to develop crystalline grains, while also more species for faster growth of the crystallites are available. © 1994 American Institute of Physics.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Amsterdam : Elsevier
    Journal of Crystal Growth 126 (1993), S. 505-509 
    ISSN: 0022-0248
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Chemistry and Pharmacology , Geosciences , Physics
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    Amsterdam : Elsevier
    Thin Solid Films 174 (1989), S. 5-9 
    ISSN: 0040-6090
    Source: Elsevier Journal Backfiles on ScienceDirect 1907 - 2002
    Topics: Physics
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Materialwissenschaft und Werkstofftechnik 29 (1998), S. 476-483 
    ISSN: 0933-5137
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Stress anisotropy and structure of TiN thin filmsIn many sputtering processes the substrate is rotated or periodically moved with respect to the target in order to obtain a homogeneous film deposition. In that case anisotropic conditions of film growth exist which lead to anisotropic mechanical stresses. The stress anisotropy depends on the carrier velocity and can be attributed to the film structure. The stress measurements, therefore, will be related to measurements of composition by SNMS, to determination of stoichiometry by ellipsometry and to investigations of structure by X-ray diffraction.
    Notes: Bei Sputterprozessen wird häufig das Substrat unter dem Sputtertarget rotiert oder hin- und herbewegt, um eine gleichmäßige Beschichtung zu erzielen. In dieser Arbeit wird gezeigt, daß dabei anisotrope Wachstumsbedingungen bestehen, die zu anisotropen mechanischen Spannungen führen. Die Größe der Spannungsanisotropie hängt von der Transportgeschwindigkeit ab und läßt sich durch die dabei erzeugte Schichtstruktur interpretieren. Die Messungen der Schichtspannungen werden deshalb korreliert mit der Bestimmung der Zusammensetzung mit SNMS, mit Untersuchungen der Stöchiometrie mit Hilfe von ellipsometrischen Messungen sowie mit Untersuchungen der Schichtstruktur mit Hilfe von Röntgenbeugung.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
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