ISSN:
0894-3230
Keywords:
Organic Chemistry
;
Physical Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Physics
Notes:
The secondary α-deuterium isotpe effect on the equiliburium constant (KD/KH) for the hydration of p-nitrobenzaldehyde is 1·39 ± 0·05. The Kinetic secondary α-deuterium isotope effect (KD/KH) for the addition of water to p-nitrobenzaldehyde is 1·18 ± 0·07. This result demonstrates that there is extensive carbon-oxygen bond formation in the transition state for addition of water to the carbonyl group of p-nitrobezaldehyde.
Additional Material:
3 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/poc.610070405
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