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Secondary α-deuterium isotpe effect on the hydration of p-nitrobenzaldehyde (1994)

Pires, José Ricardo ; Stachissini, Antonia Sonia ; Amaral, Luciano Do

Chichester : Wiley-Blackwell

Journal of Physical Organic Chemistry 7 (1994), S. 192-195

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ISSN: 0894-3230

Keywords: Organic Chemistry ; Physical Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology , Physics

Notes: The secondary α-deuterium isotpe effect on the equiliburium constant (KD/KH) for the hydration of p-nitrobenzaldehyde is 1·39 ± 0·05. The Kinetic secondary α-deuterium isotope effect (KD/KH) for the addition of water to p-nitrobenzaldehyde is 1·18 ± 0·07. This result demonstrates that there is extensive carbon-oxygen bond formation in the transition state for addition of water to the carbonyl group of p-nitrobezaldehyde.

Additional Material: 3 Tab.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/poc.610070405

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