ISSN:
1089-7690
Source:
AIP Digital Archive
Topics:
Physics
,
Chemistry and Pharmacology
Notes:
The intramolecular hydrogen transfer rate of o-tolyl radicals has been examined by monitoring the absorption time profile of benzyl radicals formed in the picosecond 266 nm laser photolysis of o-chlorotoluene. The rise time of the benzyl radical absorption, 6.5 ns, was attributed mostly to the rearrangement rate of o-tolyl radicals to benzyl radicals.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1063/1.450448
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