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  • 1
    ISSN: 1573-4803
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract The influence of a 3 wt% Re addition on the creep strength and microstructure of a mechanically alloyed and oxide dispersion-strengthened nickel-base superalloy was investigated. Two alloys, Ni–8Cr–6.5Al–6W–3Ta–1.5Mo–6Co–1Ti–3Re–0.15Zr–0.05C–0.01B–0.9Y2O3 (3Re alloy) and a non-rhenium containing (0Re) alloy were prepared for this study. The 3Re alloy showed two-fold improvement in creep life compared with that of 0Re alloy, presumably due to a change in the mode of the precipitate-dislocation interaction. For the 3Re alloy, finer, more cuboidal and aligned γ′ precipitates are formed, which force the mobile dislocations at the γ–γ′ interfaces to cut precipitates in order to proceed. Shearing of precipitates is evinced by the existence of stacking faults and results in an increase of creep strength. In constrast, lower creep strength was observed for 0Re alloy because a dislocation looping mode is dominant with coarser and more irregularly shaped γ′ precipitates present in this alloy. Another possible explanation for an improved creep strength of 3Re alloy is related to the tangled dislocation structure formed by the interaction between glide dislocation and interfacial dislocation, which also acts as an effective barrier for further glide dislocation motion. A 3 wt% Re addition significantly retards γ′ coarsening kinetics. Rhenium acts as a rate-controlling species upon the volume diffusion-controlled coarsening process because it is a heavy elemenet and also it almost solely partitions to the γ matrix. X-ray diffraction experiments showed that the magnitude of the lattice mismatch between γ and γ′ increased with the 3 wt% Re addition from 0% to −0.26% at room temperature. Increased lattice mismatch for 3Re alloy causes the formation of more aligned and cuboidal γ′ precipitates rather than random and odd-shaped γ′ precipitates for 0Re alloy, and it also accelerates the coalescence between cuboidal γ′ precipitates.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1573-4803
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract The coarsening behavior of γ′ precipitates with a uniform size distribution and with a bimodal size distribution in a mechanically alloyed ODS Ni-base superalloy were investigated to clarify the effect of elastic interaction energy on the coarsening behavior of γ′ precipitates. The coarsening rate decreased with increasing size of γ′ precipitates with a uniform size distribution, contrary to the classical LSW theory, and the coarsening behavior of γ′ precipitates with a bimodal size distribution exhibited Ostwald ripening in which the larger precipitates grow at the expense of smaller precipitates. The driving force for coarsening of γ′ precipitates was analyzed based on the two-particle model, considering the effect of elastic interaction energy in addition to the effect of interfacial energy. The contribution of elastic interaction energy on the total energy was found to increase with increasing size of precipitates, and the decelerated coarsening of γ′ precipitates was attributed to the decrease in the driving force for coarsening with increasing size of precipitates.
    Type of Medium: Electronic Resource
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