ISSN:
0018-019X
Keywords:
Chemistry
;
Organic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
For two series of tricyclic 1,3-diols (with tertiary-secondary and tertiary-tertiary hydroxy-groups) the existence of strong internal hydrogen bonding of the O—H…O type has been established by infrared spectrometry. The frequency shift Δν = ν(O—H)free - ν(O—H…O)intern shows values in the range 110-130 cm-1. The influence of conformation of neighbouring groups and ring conformation on the frequency shifts is discussed.
Additional Material:
2 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/hlca.19600430622
Permalink