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  • 1
    ISSN: 1572-8927
    Keywords: Excess molar volume ; viscosity ; activation energy ; surface tension ; ethanoic acid ; propanoic acid ; butanoic acid ; nitrobenzene
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Abstract Density, viscosity, and surface tension of three binary liquid systems: ethanoic acid+nitrobenzene, propanoic acid+nitrobenzene, and butanoic acid+nitrobenzene have been determined at 25, 35, and 45°C, over the whole composition range. The excess molar volumes, viscosities, Gibbs energies for the activation of flow, and surface tension were evaluated and fitted to a Redlich-Kister type of equation. The Grunberg-Nissan parameter d was also calculated. Binary viscosity data were fitted to the models of McAllister, Heric, Krishnan, and Laddha, Auslander, and Teja and Rice. Surface tension data were fitted to the models of Zihao and Jufu, Rice, and Teja, and an empirical two-constant model.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 30 (1984), S. 835-837 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 43 (1997), S. 1955-1963 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: The velocity of rise and the drag of a single vapor bubble collapsing in another immiscible liquid were measured experimentally. During the process of collapse, the dispersed-phase vapor bubble was transformed to a two-phase bubble with condensate accumulating at the rear of the two-phase bubble and vapor at its top. Such a configuration of a two-phse bubble is commonly known as a drobble. Experimental data for the six pairs of liquids covered a range of drobble (two-phase bubble) Reynolds numbers from 0.003 to 3,000. Two regimes of drobble movement were encountered. In the first regime (Re 〈 100), the drobble maintained its sphericity, and the observed drag was less than the solid-sphere drag predicted by the established solid sphere or Hadamard et al. fluid-sphere drag models. In the second regime, the drobble was deformed and oscillated; the observed drag departed suddenly from predictions of spherical models and increased with increasing Reynolds numbers. The critical Reynolds number covered a range from 100 to 1,000. Empirical models for drobble velocity and drag coefficient are derived.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
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