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  • 1
    Electronic Resource
    Electronic Resource
    Westerville, Ohio : American Ceramics Society
    Journal of the American Ceramic Society 82 (1999), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The next generations of multilayer ceramic capacitors are expected to have active ceramic layer thicknesses of 3 μm or less. To retain a reliable ceramic device, it is advantageous to engineer a uniform and fine-grained microstructure. In this study, a dense ceramic (〉96% of theoretical) with fine-grained size (〈0.2 μm), and permittivity of 2800, meeting the EIA X7R temperature characteristic has been obtained using hydrothermally synthesized BaTiO3 powder with precipitation-coated additives. The temperature coefficient of capacitance (TCC) and the dissipation factor (DF) are investigated as a function of active layer thickness and compared with that of a conventional coarse-grained dielectric of similar composition and fired density. The fine-grained ceramic maintained X7R characteristic in active layers as thin as 3 μm under 1 VAC and 1 kHz test conditions. For equivalent active thickness, the DF of the fine-grained version was consistently lower than the coarse-grained material. These results indicate that an improved voltage coefficient is possible for finer-grained materials under otherwise equivalent conditions. The possible causes for this behavior are also discussed.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Westerville, Ohio : American Ceramics Society
    Journal of the American Ceramic Society 85 (2002), S. 0 
    ISSN: 1551-2916
    Source: Blackwell Publishing Journal Backfiles 1879-2005
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Preparation of dense and phase-pure Ba2Ti9O20 is generally difficult using solid-state reaction, since there are several thermodynamically stable compounds in the vicinity of the desired composition and a curvature of Ba2Ti9O20 equilibrium phase boundary in the BaO–TiO2 system at high temperatures. In this study, the effects of B2O3 on the densification, microstructural evolution, and phase stability of Ba2Ti9O20 were investigated. It was found that the densification of Ba2Ti9O20 sintered with B2O3 was promoted by the transient liquid phase formed at 840°C. At sintering temperatures higher than 1100°C, the solid-state sintering became dominant because of the evaporation of B2O3. With the addition of 5 wt% B2O3, the ceramic yielded a pure Ba2Ti9O20 phase at sintering temperatures as low as 900°C, without any solid solution additive such as SnO2 or ZrO2. The facilities of B2O3 addition to the stability of Ba2Ti9O20 are apparently due to the eutectic liquid phase which accelerates the migration of reactant species.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    s.l. ; Stafa-Zurich, Switzerland
    Key engineering materials Vol. 351 (Oct. 2007), p. 48-51 
    ISSN: 1013-9826
    Source: Scientific.Net: Materials Science & Technology / Trans Tech Publications Archiv 1984-2008
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: In this study, the feasibility for use of multiphase BaTiO3 ceramics as microwavedielectric resonators was evaluated through the substitution of metal ions in B sites, such as ions ofMn, Co, Mg, In, Fe, Zn, and Ni. The effects of metal ions substitution and sintering conditions onthe densification, microstructural evolution and microwave properties of the BaTiO3 ceramicscontaining cubic and hexagonal phase were examined
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    s.l. ; Stafa-Zurich, Switzerland
    Materials science forum Vol. 426-432 (Aug. 2003), p. 3385-3390 
    ISSN: 1662-9752
    Source: Scientific.Net: Materials Science & Technology / Trans Tech Publications Archiv 1984-2008
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
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